(S)-(+)-4-甲基-2-戊醇合成路线 （共 11 条）
反应条件
methanesulfonic acid; (R,R)-dihydroborate in pentane T=-20°C; 48 h; Title compound not separated from byproducts;
参考文献
Imai, Toshiro; Tamura, Tadashi; Yamamuro, Akira; Sato, Tsuneo; Wollmann, Theodor A.; et al.
Journal of the American Chemical Society, 1986 , vol. 108, # 23 p. 7402 - 7404
反应条件
[(R)-1,1'-binaphthyl-2,2'-diyldioxy]{bis[(S)-(1-phenylethyl)]amino}phosphine; bis(acetylacetonate)nickel(II) in tetrahydrofuran; hexane T=-20°C; 6 h; Title compound not separated from byproducts;
参考文献
Angewandte Chemie - International Edition, , vol. 44, # 15 p. 2232 - 2234
反应条件
immobilized lipase B from Candida antarctica in hexane T=32°C; 1 h; Resolution of racemateEnzymatic reaction;
参考文献
Molecules, , vol. 17, # 8 p. 8955 - 8967,13
Molecules, , vol. 17, # 8 p. 8955 - 8967
反应条件
beta-hydroxyethylmercaptan; Tris-HCl buffer; alcohol dehydrogenase from Thermoanaerobium brockii; NADP; isopropyl alcohol T=37°C; pH = 8.50, 50 percent conversion;
参考文献
Journal of the American Chemical Society, , vol. 108, p. 162
反应条件
1: 1.) n-BuLi / 1.) THF, 0 deg C, 15 min, 2.) room temp., overnight 2: 83 percent Spectr. / diborane / toluene / -78 °C 3: Raney Ni View Scheme
参考文献
Journal of Organic Chemistry, , vol. 47, # 7 p. 1196 - 1200
反应条件
1: 83 percent Spectr. / diborane / toluene / -78 °C 2: Raney Ni View Scheme
参考文献
Journal of Organic Chemistry, , vol. 47, # 7 p. 1196 - 1200
反应条件
ethanol; nickel P=1520 Torr;
参考文献
Journal of the Chemical Society, , p. 1452
Journal of the Chemical Society, , p. 1451
反应条件
nickel Yield given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Journal of Organic Chemistry, , vol. 47, # 7 p. 1196 - 1200
反应条件
methanol; sodium hydroxide; dihydrogen peroxide; (-)-Monoisopinocampheylborane 1.) THF, -25 deg C, 11 h, 2.) 55 deg C, 1 h; Yield given. Multistep reaction. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Journal of Organic Chemistry, , vol. 47, # 26 p. 5074 - 5083
反应条件
ueber das Brucinsalz des sauren Phthalsaeureesters;
参考文献
Journal of the Chemical Society, , p. 2153
