hexamethyl-benzene in dichloromethane-d2 mixt. of Fe-complex, hexamethylbenzene standard (molar ratio 1:0.25) and CD2Cl2 cooled to -40°C, 1 equiv of CF3SO3H added; without isolation; monitored by (1)H NMR spectra;
参考文献
Blakeney, Andrew J.; Johnson, Dennis Lee; Donovan, Patrick W.; Gladysz, J. A.
Inorganic Chemistry, 1981 , vol. 20, p. 4415 - 4419
CO in dichloromethane CH2Cl2 was distilled into tube contg. of PPN(Ru4N(CO)12), CO was bubbled through the soln. for 10 min, CF3SO3H was added; the volume was reduced, hexane was added, soln. was filtered, residue was extd. with hexane, filtrate was chromd.; elem. anal.;
参考文献
Journal of the American Chemical Society, , vol. 108, # 9 p. 2301 - 2309
CO in dichloromethane CH2Cl2 was distilled into tube contg. of PPN(FeRu3N(CO)10(P(OMe)3)2), CO was bubbled through the soln. for 10 min, CF3SO3H was added; the volume was reduced, oil was extd. with hexane, filtrate was chromd.; elem. anal.;
参考文献
Journal of the American Chemical Society, , vol. 108, # 9 p. 2301 - 2309
in further solvent(s) Ru-complex in CF3SO3H (detection of intermediates by NMR spectroscopy); pouring onto ice; extn. (pentane or CH2Cl2), evapn., thin layer chromy. (SiO2);
参考文献
Bower, David K.; Keister, Jerome B.
Organometallics, 1990 , vol. 9, p. 2321 - 2327
