(Z)-7-十二碳烯-1-醇乙酸酯合成路线 （共 65 条）
反应条件
1: LiAlH4
2: pyridine
View Scheme
参考文献
Bykov; Goletiani; Butenko; Finkel'shtein
Doklady Chemistry, 2002 , vol. 384, # 4-6 p. 163 - 166
反应条件
1: Cp2ZrHCl; HCl
2: 9-BBN; t-BuOK
3: LiAlH4
4: pyridine
View Scheme
参考文献
Bykov; Goletiani; Butenko; Finkel'shtein
Doklady Chemistry, 2002 , vol. 384, # 4-6 p. 163 - 166
反应条件
WCl4(O-2,6-C6H3Cl2)2; tetramethylstannane in chlorobenzene
T=85°C; 4 h; Yield given;
参考文献
Crisp, Geoffrey T.; Collis, Maree P.
Australian Journal of Chemistry, 1988 , vol. 41, # 6 p. 935 - 942
反应条件
1: Na, liq. NH3 / diethyl ether
2: NaNH2 / diethyl ether
3: H2 / Lindlar catalyst / methanol
4: NaI / dimethylsulfoxide
View Scheme
参考文献
Kovaleva,A.S. et al.
Journal of Organic Chemistry USSR (English Translation), 1972 , vol. 8, p. 2523 - 2527
Zhurnal Organicheskoi Khimii, 1972 , vol. 8, p. 2474 - 2479
反应条件
1: NaNH2 / diethyl ether
2: H2 / Lindlar catalyst / methanol
3: NaI / dimethylsulfoxide
View Scheme
参考文献
Kovaleva,A.S. et al.
Journal of Organic Chemistry USSR (English Translation), 1972 , vol. 8, p. 2523 - 2527
Zhurnal Organicheskoi Khimii, 1972 , vol. 8, p. 2474 - 2479
反应条件
1: H2 / Lindlar catalyst / methanol
2: NaI / dimethylsulfoxide
View Scheme
参考文献
Kovaleva,A.S. et al.
Journal of Organic Chemistry USSR (English Translation), 1972 , vol. 8, p. 2523 - 2527
Zhurnal Organicheskoi Khimii, 1972 , vol. 8, p. 2474 - 2479
反应条件
1: 55 g / Me4Sn / MoCl5/SiO2 / toluene / 24 h / 20 °C
2: 90 percent / LiAlH4; Cp2ZrCl2 / tetrahydrofuran / 1 h / 20 °C
3: 55 percent / 9-BBN; t-BuOK / 2-methyl-propan-2-ol
4: 95 percent / LiAlH4 / tetrahydrofuran / 1 h / 50 °C
5: 95 percent / pyridine / hexane / 2 h
View Scheme
参考文献
Bykov; Butenko; Egupova; Finkelshtein
Russian Chemical Bulletin, 2000 , vol. 49, # 7 p. 1301 - 1304
反应条件
1: p-TsOH / methanol / 2 h / Heating
2: 95 percent / H2, quinoline / Lindlar catalyst / pentane / 1 h / -10 °C
3: 95 percent / pyridine / diethyl ether
View Scheme
参考文献
Rossi, Renzo; Carpita, Adriano; Gaudenzi, Loretta; Quirici, Maria Grazia
Gazzetta Chimica Italiana, 1980 , vol. 110, # 4 p. 237 - 246
反应条件
1: 1.) 2M BuLi / 1.) hexane, HMPT, 0 deg C, 30 min, 2.)THF, r. t., 12 h
2: p-TsOH / methanol / 2 h / Heating
3: 95 percent / H2, quinoline / Lindlar catalyst / pentane / 1 h / -10 °C
4: 95 percent / pyridine / diethyl ether
View Scheme
参考文献
Rossi, Renzo; Carpita, Adriano; Gaudenzi, Loretta; Quirici, Maria Grazia
Gazzetta Chimica Italiana, 1980 , vol. 110, # 4 p. 237 - 246
反应条件
1: 90 percent / p-TsOH / diethyl ether
2: 1.) 2M BuLi / 1.) hexane, HMPT, 0 deg C, 30 min, 2.)THF, r. t., 12 h
3: p-TsOH / methanol / 2 h / Heating
4: 95 percent / H2, quinoline / Lindlar catalyst / pentane / 1 h / -10 °C
5: 95 percent / pyridine / diethyl ether
View Scheme
参考文献
Rossi, Renzo; Carpita, Adriano; Gaudenzi, Loretta; Quirici, Maria Grazia
Gazzetta Chimica Italiana, 1980 , vol. 110, # 4 p. 237 - 246
