in neat (no solvent) byproducts: HF; mixing of HN3/N2 with F2/N2 (coiled copper tube), caution (inside blastshield); sepn. of HF (NaF trap); detn. by IR, UV spectroscopy;
参考文献
Gmelin Handbook: F: SVol.1, 72, page 247 - 248
Full Text Show Details
Haller, J. F.
Diss. Cornell Univ. 1942
in neat (no solvent) byproducts: AsF5, F2N2; vac. thermolyses; not isolated, detected by FT-IR;
参考文献
Netzloff, Heather M.; Gordon, Mark S.; Christe, Karl; Wilson, William W.; Vij, Ashwani; Vij, Vandana; Boatz, Jerry A.
Journal of Physical Chemistry A, 2003 , vol. 107, # 34 p. 6638 - 6647
in neat (no solvent) byproducts: CsSbF6, F2N2; not isolated, detected by FT-IR;
参考文献
Netzloff, Heather M.; Gordon, Mark S.; Christe, Karl; Wilson, William W.; Vij, Ashwani; Vij, Vandana; Boatz, Jerry A.
Journal of Physical Chemistry A, 2003 , vol. 107, # 34 p. 6638 - 6647
→
反应条件
in neat (no solvent) a mixt. of a small excess of F2 and HN3 dild. with N2 is passed through a spiral tube of copper into two cold traps (the first cooled with aceton/CO2, the second with liq. air);; ppt. in the second cold trap; fractional distn. (explosion possible);;
参考文献
Gmelin Handbook: F: SVol.1, 72, page 247 - 248
Full Text Show Details
Haller, J. F.
Diss. Cornell Univ. 1942
in gaseous matrix
Kinetics; byproducts: N2; other Radiation; pyrolysis by CO2-laser pulse; Ar as carrier gas; SF6 as sensitizer; visible spectra collected by a optical multichannel analyzer; UV emission;
参考文献
Benard, D. J.; Chowdhury, M. A.; Winker, B. K.; Seder, T. A.; Michels, H. H.
Journal of Physical Chemistry, 1990 , vol. 94, # 19 p. 7507 - 7514
