in gaseous matrix
Kinetics; reaction of in situ generated ClO moleculs (by photolysis) with in situgenerated NO3 radical (N2 diluent, atmospheric pressure, 296 K, static conditions); monitoring by UV spectroscopy;
参考文献
Cox, R. A.; Fowles, Martin; Moulton, David; Wayne, Richard P.
Journal of Physical Chemistry, 1987 , vol. 91, # 12 p. 3361 - 3365
in neat (no solvent)
Kinetics; HO2 reacted with OCl at 220-336 K in He carrier gas at 1.5 Torr;
参考文献
Burrows, John P.; Cox, Richard A.
Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases, 1981 , vol. 77, p. 2465 - 2480
Balard
Liebigs Annalen der Chemie, 1835 , vol. 14, p. 178 - 178
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Balard
Ann. Chim. Phys., 1834 , vol. 57, p. 259 - 259
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Gmelin Handbook: Cl: MVol., 152, page 410 - 411
ammonia in water
Kinetics; the ratio of NH3 and NaOCl is 2:3 at 15-25°C; the rate of react. depends on the concn. of OH ion and NH3; the react. is faster in the presence of CuSO4 and other heavy metal; in the large excess of NaOCl fast but not quantitative reaction;
参考文献
Gmelin Handbook: NH4: MVol.1, 1.5, page 12 - 20
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Oryng, T.
Dissert. Heidelberg 1910, S. 1-39.
