in gas
Kinetics; in a discharge flow system; He sweeped through a perforator with 0.1 M aq. soln. of HOCl then through a cooled water trap; mixed with H/He passing through a mixing cell into reaction tube (duranglass); reacted at room temp. and 2.0 mbar; not isolated, detected by mass-spectrometry, OH-resonance fluorescence;
参考文献
Vogt, R.; Schindler, R.N.
Berichte der Bunsen-Gesellschaft, 1993 , vol. 97, # 6 p. 819 - 829
in gas
Kinetics; in a discharge flow system; He sweeped through a perforator with 0.1 M aq. soln. of HOCl then through a cooled water trap; mixed with Cl/He passing through a mixing cell into reaction tube (duranglass); reacted at room temp. and 2.0 mbar; not isolated, detected by mass-spectrometry, OH-resonance fluorescence;
参考文献
Vogt, R.; Schindler, R.N.
Berichte der Bunsen-Gesellschaft, 1993 , vol. 97, # 6 p. 819 - 829
Kinetics; reaction of components in discharge fast-flow tube at 213, 243, 273 or 298 K (HOCl introducing by He bubbling through aq. HOCl soln., O generated in situ, p(total)=2 mbar v= 2.9-5.8 m/s); mass spectrometric monitoring;
参考文献
Schindler, Ralph N.; Dethlefs, Jan; Schmidt, Mark
Berichte der Bunsengesellschaft/Physical Chemistry Chemical Physics, 1996 , vol. 100, # 7 p. 1242 - 1249
in gas
Kinetics; in a discharge flow system; He sweeped through a perforator with 0.1 M aq. soln. of HOCl then through a cooled water trap; dild. (He); mixed with F/He passing through a mixing cell into reaction tube (duranglass); reacted at room temp. and 2.0-2.2 mbar; not isolated, detected by mass-spectrometry, OH-resonance fluorescence;
参考文献
Vogt, R.; Schindler, R.N.
Berichte der Bunsen-Gesellschaft, 1993 , vol. 97, # 6 p. 819 - 829
hydrogen sulfide in water
react. of aq. solns. of H2S and HClO;; product mixture of S and H2SO4, but no thiosulfate and polythionate obtained; also no pure S obtained, when H2S:HClO = 1:1 or H2S in excess;;
参考文献
Stamm, H.; Goehring, M.
Ber., 1943 , vol. 76, p. 737 - 742
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Gmelin Handbook: S: MVol.B1, 43, page 94 - 95
hydrogenchloride in hydrogenchloride
Kinetics; at 20°C;;
参考文献
Eigen, M.; Kustin, K.
Journal of the American Chemical Society, 1962 , vol. 84, p. 1355 - 1361
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Gmelin Handbook: Cl: SVol.B2, 35, page 391 - 393
