2,3-二甲基苯甲酸甲酯合成路线 （共 16 条）
反应条件
1: 98.5 percent / LiAlH4 / diethyl ether / 1.) reflux, 3 h, 2.) room temp., overnight 2: 80.1 percent / PCC / CH2Cl2 / 2 h / Ambient temperature 3: 90.7 percent / pyridine, piperidine / 48 h / 80 °C View Scheme
参考文献
Neudeck
Monatshefte fur Chemie, 1996 , vol. 127, # 2 p. 185 - 200
反应条件
(alkaline hydrolysis);
参考文献
Acheson,R.M.; Flowerday,R.F.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1974 , p. 2339 - 2342
反应条件
1: 98.5 percent / LiAlH4 / diethyl ether / 1.) reflux, 3 h, 2.) room temp., overnight 2: 80.1 percent / PCC / CH2Cl2 / 2 h / Ambient temperature View Scheme
参考文献
Neudeck
Monatshefte fur Chemie, 1996 , vol. 127, # 2 p. 185 - 200
反应条件
1: 98.5 percent / LiAlH4 / diethyl ether / 1.) reflux, 3 h, 2.) room temp., overnight 2: 90.4 percent / SOCl2, pyridine / benzene / 1.) reflux, 1 h, 2.) room temp., 14 h View Scheme
参考文献
Neudeck
Monatshefte fur Chemie, 1996 , vol. 127, # 2 p. 185 - 200
反应条件
lithium aluminium tetrahydride in diethyl ether 1.) reflux, 3 h, 2.) room temp., overnight;
参考文献
Neudeck
Monatshefte fur Chemie, 1996 , vol. 127, # 2 p. 185 - 200
反应条件
1: NBS, benzoyl peroxide / CCl4 / 7 h / Heating
2: 80 percent / 1 h / 180 °C / 10 Torr
3: H2, Ca(OH)2 / 10percent Pd/C / dioxane / 48 h / 2068.6 Torr
View Scheme
参考文献
Neudeck
Monatshefte fur Chemie, 1996 , vol. 127, # 2 p. 201 - 217
