1-苄基-2,3-异亚丙基-rac-甘油合成路线 （共 27 条）
反应条件
1: AcOH / propan-2-ol; H2O / 6 h / Heating 2: 30 percent / Py / CHCl3 / 48 h / 20 °C View Scheme
参考文献
Takahashi, Toshihiro; Ido, Tatsuo; Nagata, Shinji; Iwata, Ren
Journal of Labelled Compounds and Radiopharmaceuticals, 2000 , vol. 43, # 9 p. 943 - 969
反应条件
1: 11.74 g / Amberlyst 15 / methanol / 5 h / 20 °C
2: Pseudomonas cepacia lipase / tetrahydrofuran; hexane
View Scheme
参考文献
Guanti, Giuseppe; Banfi, Luca; Basso, Andrea; Bevilacqua, Elisabetta; Bondanza, Laura; Riva, Renata
Tetrahedron Asymmetry, 2004 , vol. 15, # 18 p. 2889 - 2892
反应条件
1: 34.6 percent / aq. HCl / tetrahydrofuran / 12 h / Ambient temperature
2: 22.8 percent
View Scheme
参考文献
Ctech, Bronislav
Tetrahedron Letters, 1980 , vol. 21, p. 4197 - 4198
反应条件
1: H2O / hydrolysis
2: 25 percent
View Scheme
参考文献
Ctech, Bronislav
Tetrahedron Letters, 1980 , vol. 21, p. 4197 - 4198
反应条件
zinc(II) chloride
T=20°C; 15 h;
参考文献
Nifantyev, E. E.; Predvoditelev, D. A.; Fursenko, I. V.; Smirnova, L. I.
Synthesis, 1982 , # 2 p. 132 - 134
反应条件
1: AcOH / propan-2-ol; H2O / 6 h / Heating
2: 30 percent / Py / CHCl3 / 48 h / 20 °C
3: 79 percent / Et3N / benzene / 1 h / Heating
View Scheme
参考文献
Howe; Malkin
Journal of the Chemical Society, 1951 , p. 2666
反应条件
1: MgBr2 / benzene / 24 h / Heating
2: 70 percent / pyridine / Ambient temperature
3: NaH / tetrahydrofuran / Heating
4: MgBr2 / benzene / 24 h / Heating
View Scheme
参考文献
Haraldsson, Gudmundur G.; Stefansson, Thorarinn; Snorrason, Halldor
Acta Chemica Scandinavica, 1998 , vol. 52, # 6 p. 824 - 826
