7-三乙基硅烷基-13-氧代浆果赤霉素III合成路线 （共 2 条）
反应条件
1: 94 percent Turnov. / NaBH4 / methanol / 3 h / 25 °C 2: 86 percent Turnov. / NaN(SiMe3)2 / tetrahydrofuran / 0.5 h / 0 °C 3: 80 percent / HF*pyridine / tetrahydrofuran / 1.25 h / 25 °C View Scheme
参考文献
Nicolaou; Nantermet; Ueno; Guy; Couladouros; Sorensen
Journal of the American Chemical Society, 1995 , vol. 117, # 2 p. 624 - 633
反应条件
1: 79 percent / NaBH4 / methanol / 2 h 2: 85 percent / HF*Py / tetrahydrofuran / 2 h View Scheme
参考文献
Masters, John J.; Link, J. T.; Snyder, Lawrence B.; Young, Wendy B.; Danishefsky, Samuel J.
Angewandte Chemie, 1995 , vol. 107, # 16 p. 1886 - 1888
