4-羟基-3-甲基色烯-2-酮合成路线 （共 19 条）
反应条件
triethylamine in tetrahydrofuran
T=80°C; P=7355.08 Torr; 4 h;
参考文献
Mizuno, Takumi; Nishiguchi, Ikuzo; Hirashima, Tsuneaki; Ogawa, Akiya; Kambe, Nobuaki; Sonoda, Noboru
Synthesis, 1988 , # 3 p. 257 - 259
反应条件
sodium hydride in benzene
72 h; Heating;
参考文献
Silverman, Richard B.
Journal of the American Chemical Society, 1981 , vol. 103, # 13 p. 3910 - 3915
反应条件
sodium ditelluride in tetrahydrofuran
T=-20 - 20°C;
参考文献
Dittmer, Donald C.; Li, Qun; Avilov, Dimitry V.
Journal of Organic Chemistry, 2005 , vol. 70, # 12 p. 4682 - 4686
反应条件
hydrogenchloride in ethanol
参考文献
Morris, Joel; Luke, George P.; Wishka, Donn G.
Journal of Organic Chemistry, 1996 , vol. 61, # 9 p. 3218 - 3220
反应条件
sodium cyanoborohydride in methanol
40 h; Heating;
参考文献
Appendino, Giovanni; Cravotto, Giancarlo; Tagliapietra, Silvia; Ferraro, Stefano; Nano, Gian Mario; Palmisano, Giovanni
Helvetica Chimica Acta, 1991 , vol. 74, # 7 p. 1451 - 1458
反应条件
hydrogen; Raney-Ni W-2
2 h; Ambient temperature;
参考文献
Tabakovic, Ibro; Tabakovic, Katmerka; Gaon, Igor
Organic Preparations and Procedures International, 1997 , vol. 29, # 2 p. 223 - 226
反应条件
1: 74 percent / AcOH, pyridine / ethanol / 48 h / Heating
2: 75 percent / H2 / Raney-Ni W-2 / 2 h / Ambient temperature
View Scheme
参考文献
Tabakovic, Ibro; Tabakovic, Katmerka; Gaon, Igor
Organic Preparations and Procedures International, 1997 , vol. 29, # 2 p. 223 - 226
反应条件
1: 50 percent / Na2Te / tetrahydrofuran / -20 - 20 °C
2: 77 percent / CH2Cl2 / 20 °C
3: 54 percent / Na2Te / tetrahydrofuran / -20 - 20 °C
View Scheme
参考文献
Dittmer, Donald C.; Li, Qun; Avilov, Dimitry V.
Journal of Organic Chemistry, 2005 , vol. 70, # 12 p. 4682 - 4686
反应条件
1: NaHMDS / tetrahydrofuran / -20 °C
2: 77 percent / CH2Cl2 / 20 °C
3: 54 percent / Na2Te / tetrahydrofuran / -20 - 20 °C
View Scheme
参考文献
Dittmer, Donald C.; Li, Qun; Avilov, Dimitry V.
Journal of Organic Chemistry, 2005 , vol. 70, # 12 p. 4682 - 4686
反应条件
1: 77 percent / CH2Cl2 / 20 °C
2: 54 percent / Na2Te / tetrahydrofuran / -20 - 20 °C
View Scheme
参考文献
Dittmer, Donald C.; Li, Qun; Avilov, Dimitry V.
Journal of Organic Chemistry, 2005 , vol. 70, # 12 p. 4682 - 4686
