2-氨基-4,5-二甲基苯甲酸合成路线 （共 8 条）
参考文献
Altmann, Karl-Heinz; Bold, Guido; Furet, Pascal; Manley, Paul William; Wood, Jeanette Marjorie; Ferrari, Stefano; Hofmann, Francesco; Mestan, Jurgen; Huth, Andreas; Kruger, Martin; Seidelmann, Dieter; Menrad, Andreas; Haberey, Martin; Thierauch, Karl-Heinz
Patent: US2002/19414 A1, 2002 ;
反应条件
hydrogen; palladium on activated charcoal in acetic acid
参考文献
Braendstroem,A.; Carlsson,A.I.
Acta Chemica Scandinavica (1947-1973), 1967 , vol. 21, p. 983 - 992
反应条件
1: AlCl3 / CS2
2: aq. NaOCl
3: liq. NH3, KOH / Cu
View Scheme
参考文献
Braendstroem,A.; Carlsson,A.I.
Acta Chemica Scandinavica (1947-1973), 1967 , vol. 21, p. 983 - 992
反应条件
1: (i) NaNO2, aq. HCl, (ii) /BRN= 3587243/, CuCN, aq. Na2CO3, toluene
2: aq. H2SO4
3: H2 / Pd-C / acetic acid
View Scheme
参考文献
Braendstroem,A.; Carlsson,A.I.
Acta Chemica Scandinavica (1947-1973), 1967 , vol. 21, p. 983 - 992
反应条件
1: (i) (nitration), (ii) (hydrolysis)
2: (i) NaNO2, aq. HCl, (ii) /BRN= 3587243/, CuCN, aq. Na2CO3, toluene
3: aq. H2SO4
4: H2 / Pd-C / acetic acid
View Scheme
参考文献
Braendstroem,A.; Carlsson,A.I.
Acta Chemica Scandinavica (1947-1973), 1967 , vol. 21, p. 983 - 992
反应条件
1: 98 percent / NaOH / H2O
2: 84 percent / NaOCl; NaOH
View Scheme
参考文献
Godinez, Carlos E.; Zepeda, Gerardo; Mortko, Christopher J.; Dang, Hung; Garcia-Garibay, Miguel A.
Journal of Organic Chemistry, 2004 , vol. 69, # 5 p. 1652 - 1662
反应条件
1: 90 percent / benzene / 80 °C
2: 98 percent / yellow sulfur; I2 / decahydronaphthalene; diphenyl ether / 182 °C
3: 98 percent / NaOH / H2O
4: 84 percent / NaOCl; NaOH
View Scheme
参考文献
Godinez, Carlos E.; Zepeda, Gerardo; Mortko, Christopher J.; Dang, Hung; Garcia-Garibay, Miguel A.
Journal of Organic Chemistry, 2004 , vol. 69, # 5 p. 1652 - 1662
反应条件
potassium hydroxide; ammonia; copper
参考文献
Braendstroem,A.; Carlsson,A.I.
Acta Chemica Scandinavica (1947-1973), 1967 , vol. 21, p. 983 - 992
