反应条件
sodium chloride in diethyl ether; hexane
(CH3O)2C6H4 in ether and C4H9Li in hexane mixed and stirred at 25°C for 3 d, cooled down to -196°C, NO2Cl added, warmed quickly to -95°C, stored for 2 h between -90 and -70°C, stirred and warmed to 25°C for 1.5 h; NaCl added, filtered, aq. phase extd. (ether), org. phase and solid combined, solvent removed, CH2Cl2 added, filtered (Al2O3), washed (CH2Cl2), solvent removed, recrystd. (CH2Cl2/CH3OH); elem. anal., IR, NMR, mass spectroscopy;
参考文献
Heuer, Lutz; Schmutzler, Reinhard; Schomburg, Dietmar
Zeitschrift fuer Naturforschung, B: Chemical Sciences, 1989 , vol. 44, # 8 p. 911 - 916
