120°C, 120 h; in sealed tube; molar ratio based on GeI4: 0.55;

in neat (no solvent) heating in a closed tube at 130-135°C, 10 days;; traces of (CF3)2GeI2;;

120°C, 120 h; in sealed tube; molar ratio based on GeI4: 0.98;

in neat (no solvent) heating 0.25 mol GeI2 and 0.61 mol CF3I at 150°C, 10 days, removing excessive CF3I and distillation;; (CF3)2GeI2 / CF3GeI3 = 1 / 3.5;;

in neat (no solvent) heating in a closed tube from -196 to 25°C and storing at 20°C for 48 hours;;

暂无反应条件数据

water reaction in water in presence of Ag2O;;

byproducts: fluoro olefines, cyclic fluoro chloro carbon hydrogens;

byproducts: fluoro olefines, cyclic fluoro chloro carbon hydrogens;

H3PO4; NaBD4 in water 30percent H3PO4 placed in a flask and attached to a vacuum line via a reflux condenser kept at -20°C, addn. (CF3)GeI3 to ice-cooled acid, soln. NaBD4/H2O added over 1h (pressure maintained at 600 mbar), evolved gases collected (2 traps, -196°C); fractional condensation, isothermal distn. at 0°C (slit tube column), not isolated, detected by NMR-spect.;