4,7-二溴-2,1,3-苯并噻二唑合成路线 （共 42 条）
反应条件
hydrogen bromide; bromine Inert atmosphere;
参考文献
Akpinar, Hava; Balan, Abidin; Baran, Derya; Uenver, Elif Koese; Toppare, Levent
Polymer, 2010 , vol. 51, # 26 p. 6123 - 6131
反应条件
hydrogen bromide; bromine T=120°C; 16 h;
参考文献
NITTO DENKO CORPORATION; RACHWAL, STANISLAW; WANG, PENG; RACHWAL, BOGUMILA; ZHANG, HONGXI; YAMAMOTO, MICHIHARU
Patent: US2013/74927 A1, 2013 ;
Location in patent: Paragraph 0274; 0275 ;
反应条件
1: With thionyl chloride Heating; 2: With bromine in hydrogen bromide Heating; Further stages.;
参考文献
Journal of Molecular Structure, , vol. 875, # 1-3 p. 364 - 371
参考文献
Chemistry of Heterocyclic Compounds (New York, NY, United States), , vol. 9, p. 293 - 295
Khimiya Geterotsiklicheskikh Soedinenii, , vol. 9, # 3 p. 319 - 321
反应条件
1: SO3/H2SO4 / 125 - 130 °C 2: aq. Br2 View Scheme
参考文献
Chemistry of Heterocyclic Compounds (New York, NY, United States), , vol. 9, p. 293 - 295
Khimiya Geterotsiklicheskikh Soedinenii, , vol. 9, # 3 p. 319 - 321
反应条件
cesium fluoride; NCP-pincer palladacycle in 1,4-dioxane T=130°C; 18 h;
参考文献
Mancilha, Fabiana S.; DaSilveira Neto, Brenno A.; Lopes, Aline S.; Moreira Jr., Paulo F.; Quina, Frank H.; Goncalves, Reinaldo S.; Dupont, Jairton
European Journal of Organic Chemistry, 2006 , # 21 p. 4924 - 4933
反应条件
sodium carbonate; tetrakis(triphenylphosphine) palladium(0) in ethanol; benzene Suzuki coupling; Title compound not separated from byproducts.;
参考文献
Dincalp, Haluk; Cimen, Oguzhan; Ameri, Tayebeh; Brabec, Christoph J.; Icli, Siddik
Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy, 2014 , vol. 128, p. 197 - 206
反应条件
1,1'-bis-(diphenylphosphino)ferrocene; copper(I) bromide dimethylsulfide complex; Pd[P(o-tol)3]2; caesium carbonate in tetrahydrofuran; 1-methyl-pyrrolidin-2-one T=50°C; Inert atmosphereMolecular sieve;
参考文献
Shimizu, Kenta; Minami, Yasunori; Nakao, Yoshiaki; Ohya, Ken-Ichiro; Ikehira, Hideyuki; Hiyama, Tamejiro
Chemistry Letters, 2013 , vol. 42, # 1 p. 45 - 47
反应条件
1: 85 percent / NaBH4 / ethanol / 20 h / 0 °C 2: 88 percent / SeO2 / H2O / 2 h / Heating View Scheme
参考文献
Oektem, Goezde; Balan, Abidin; Baran, Derya; Toppare, Levent
Chemical Communications, 2011 , vol. 47, # 13 p. 3933 - 3935
反应条件
bis-triphenylphosphine-palladium(II) chloride; triethylamine; copper(I) bromide T=90°C; Sonogashira cross-coupling reaction; 48 h;
参考文献
Akhtaruzzaman; Tomura, Masaaki; Zaman, Md. Badruz; Nishida, Jun-ichi; Yamashita, Yoshiro
Journal of Organic Chemistry, 2002 , vol. 67, # 22 p. 7813 - 7818
