(R)-(+)-1-苯基乙醇合成路线 (共 353 条)
反应条件
2-methoxy-phenol in various solvent(s) T=20°C; horseradish peroxydase, pH=6; Rate constantEquilibrium constant;
参考文献
Angewandte Chemie, , vol. 105, # 12 p. 1800 - 1801
反应条件
hydrogen cation in water Yield given;
参考文献
Chemische Berichte, , vol. 117, # 4 p. 1330 - 1354
反应条件
chiral 2-(3',5'-di-tert-butylphenyl)-4,4,8-trimethyl-2-phosphabicylolt;3.3.0gt;octane in n-heptane 1 h; Ambient temperatureother catalyst; var. temp.; other carbinols; Product distribution;
参考文献
Journal of the American Chemical Society, , vol. 121, # 24 p. 5813 - 5814
反应条件
Novozym 435; potassium tert-butylate; sodium carbonate; [2,3,4,5-Ph4(η5-C4CNH(i-Pr))]Ru(CO)2Cl in toluene T=25°C; 96 h;
参考文献
Journal of Organic Chemistry, , vol. 69, # 6 p. 1972 - 1977
反应条件
Novozym 435; potassium tert-butylate; sodium carbonate; [2,3,4,5-Ph4(η5-C4CNH(i-Pr))]Ru(CO)2Cl in toluene T=25°C; 72 h;
参考文献
Journal of Organic Chemistry, , vol. 69, # 6 p. 1972 - 1977
反应条件
titanium tetrachloride; 2,2'-[trans-(R,R)-1,2-cyclohexanediylbis(N-methylaminomethyl)]-diphenol in dichloromethane T=-60°C; 72 h; Title compound not separated from byproducts;
参考文献
Tetrahedron Asymmetry, , vol. 16, # 3 p. 605 - 608
反应条件
lithium aluminium tetrahydride in diethyl ether
参考文献
Synlett, , # 3 p. 333 - 338
反应条件
hydrogen; potassium hydroxide; epi.-Cin.-NH2 in isopropyl alcohol T=40°C; P=45004.5 Torr; 3 h; Autoclave; optical yield given as percent eeenantioselective reaction;
参考文献
Catalysis Communications, , vol. 11, # 7 p. 584 - 587
反应条件
1: ethyl (+/-)-cis-(2-aminocyclopentyl)carbamate; 1-acetyloxyethylbenzene With Candida antarctica polyacrylamide-immobilized lipase B, Novozyme SP-435 in tert-butyl methyl ether T=28°C; 120 h; Inert atmosphereMolecular sieveEnzymatic reaction; 2: di-tert-butyl dicarbonate in tert-butyl methyl ether 0.0833333 h; optical yield given as percent eeenantioselective reaction;
参考文献
Quijada, F. Javier; Gotor, Vicente; Rebolledo, Francisca
Organic Letters, 2010 , vol. 12, # 16 p. 3602 - 3605
反应条件
Rhodium trichloride; C45H48N4O4S2; hydrogen; sodium hydroxide in methanol T=40°C; P=37503.8 Torr; 48 h; Inert atmosphere; optical yield given as percent ee;
参考文献
Tetrahedron Letters, , vol. 50, # 6 p. 688 - 692