(R)-(+)-1-苯基乙醇合成路线 （共 353 条）
反应条件
1: 84 percent / sake yeast / ethanol; H2O 2: Raney Ni W-4 View Scheme
参考文献
Tetrahedron Letters, , vol. 25, # 36 p. 3979 - 3982
反应条件
Tris-HCl buffer T=30°C; pH=7.5; 24 h; Enzymatic reaction; enantioselective reaction;
参考文献
Journal of Organic Chemistry, , vol. 74, # 4 p. 1730 - 1732
反应条件
Burkholderia cepacia lipase; C13H24N3(1+)*C36H73O14S(1-) in di-isopropyl ether T=35°C; 0.5 h; Kinetics; Reagent/catalystTime; optical yield given as percent eeenantioselective reaction;
参考文献
Abe, Yoshikazu; Hirakawa, Takuya; Nakajima, Shino; Okano, Nagisa; Hayase, Shuichi; Kawatsura, Motoi; Hirose, Yoshihiko; Itoh, Toshiyuki
Advanced Synthesis and Catalysis, 2008 , vol. 350, # 13 p. 1954 - 1958
反应条件
Eutypa lata; PDB medium in ethanol T=25°C; 192 h; Microbiological reaction; optical yield given as percent ee;
参考文献
Tetrahedron Asymmetry, , vol. 20, # 23 p. 2666 - 2672
反应条件
1: methylmagnesium bromide With Pseudoephedrine; methyllithium in tetrahydrofuran T=20°C; 2 h; Inert atmosphere; 2: benzaldehyde in tetrahydrofuran T=-78°C; 1 h; Inert atmosphere; 3: With water; ammonium chloride in tetrahydrofuran T=-78°C; Inert atmosphere;
参考文献
Bailey, William F.; Luderer, Mark R.
Arkivoc, 2010 , vol. 2010, # 8 p. 108 - 115
反应条件
Birman's catalyst; trimethylacetic anhydride; N-ethyl-N,N-diisopropylamine in dichloromethane T=20°C; 12 h; optical yield given as percent eeenantioselective reaction;
参考文献
Heterocycles, , vol. 77, # 2 p. 801 - 810
反应条件
Birman's catalyst; trimethylacetic anhydride; N-ethyl-N,N-diisopropylamine in dichloromethane T=20°C; 12 h; optical yield given as percent eeenantioselective reaction;
参考文献
Heterocycles, , vol. 77, # 2 p. 801 - 810
反应条件
(5aS,10bR)-5a,10b-dihydro-2-(pentafluorophenyl)-4H,6H-indeno[2,1-b][1,2,4]triazolo[4,3-d][1,4]oxazinium tetrafluoroborate; 3-benzylriboflavin tetraacetate; triethylamine in toluene T=20°C; 19 h; Resolution of racemateAirMolecular sieve; optical yield given as percent eeenantioselective reaction;
参考文献
Chemistry - A European Journal, , vol. 17, # 29 p. 8009 - 8013
反应条件
(5aS,10bR)-5a,10b-dihydro-2-(pentafluorophenyl)-4H,6H-indeno[2,1-b][1,2,4]triazolo[4,3-d][1,4]oxazinium tetrafluoroborate; 3-benzylriboflavin tetraacetate; triethylamine in toluene T=20°C; 4 h; Resolution of racemateAirMolecular sieve; optical yield given as percent eeenantioselective reaction;
参考文献
Chemistry - A European Journal, , vol. 17, # 29 p. 8009 - 8013
反应条件
(5aS,10bR)-5a,10b-dihydro-2-(pentafluorophenyl)-4H,6H-indeno[2,1-b][1,2,4]triazolo[4,3-d][1,4]oxazinium tetrafluoroborate; 3-benzylriboflavin tetraacetate; triethylamine in toluene T=20°C; 19 h; Resolution of racemateAirMolecular sieve; optical yield given as percent eeenantioselective reaction;
参考文献
Chemistry - A European Journal, , vol. 17, # 29 p. 8009 - 8013
