(R)-(+)-1-苯基乙醇合成路线 （共 353 条）
反应条件
1.1: potassium bromide / water / 0.17 h / 25 °C / |Resolution of racemate 1.2: 2 h / 25 °C 2.1: sodium tetrahydroborate 3.1: potassium bromide / water / 0.17 h / 25 °C / |Resolution of racemate 3.2: 2 h / 25 °C View Scheme
参考文献
Applied Catalysis A: General, , vol. 458, p. 1 - 10
反应条件
lipase B from Candida antarctica in toluene T=70°C; 48 h; Resolution of racemateEnzymatic reaction;
参考文献
European Journal of Organic Chemistry, , vol. 2014, # 14 p. 2917 - 2923
反应条件
lipase B from Candida antarctica in toluene T=70°C; 48 h; Resolution of racemateEnzymatic reaction;
参考文献
European Journal of Organic Chemistry, , vol. 2014, # 14 p. 2917 - 2923
反应条件
potassium tert-butylate; isopropyl alcohol; [RhCl(η2:η2-cycloocta-1,5-diene)]2; PhHN-C(S)-N(CH3)-CH(Ph)-CH(Ph)-N(CH3)-C(S)-NHPh 1.) 90 min; 2.) r.t., overnight, 82 deg C, 1 d; Yield given. Multistep reaction;
参考文献
Journal of Organometallic Chemistry, , vol. 567, # 1-2 p. 133 - 136
反应条件
Rh(1+)*BF4(1-); dihydrogen peroxide; (-)-bis(5-diphenylphosphono-tetrahydroindenyl)iron in toluene T=-50°C; Addition; oxidation; 12 h; 2.) H2O2, NaOH; Product distribution; Further Variations:CatalystsSolvents;
参考文献
Tetrahedron Letters, , vol. 40, # 27 p. 4977 - 4980
反应条件
roots of Apium graveolens L; var. rapaceum in phosphate buffer; acetone pH=6.2; 48 h; Title compound not separated from byproducts;
参考文献
Mczka, Wanda K; Mironowicz, Agnieszka
Tetrahedron Asymmetry, 2002 , vol. 13, # 21 p. 2299 - 2302
反应条件
HEPES buffer; Nicotiana tabacum GTF-II glucosyltransferase T=35°C; pH=7.0; 36 h; Enzymatic reaction;
参考文献
Tetrahedron Asymmetry, , vol. 15, # 15 p. 2319 - 2321
反应条件
sodium hydroxide; BES buffer; thermophile esterase in water; acetonitrile pH=7.20;
参考文献
Tetrahedron Asymmetry, , vol. 15, # 18 p. 2991 - 3004
反应条件
CAL B T=35°C; 0.5 h; Resolution of racemateEnzymatic reaction; optical yield given as percent ee;
参考文献
European Journal of Organic Chemistry, , # 36 p. 6938 - 6943
反应条件
CAL-B-conjugated magnetic nanobead T=30°C; pH=7.4; 24 h; aq. phosphate buffer; optical yield given as percent ee;
参考文献
Tetrahedron Letters, , vol. 52, # 9 p. 1041 - 1043
