反式-alpha-甲基肉桂醛合成路线 （共 62 条）
反应条件
1: 54 percent / LiOEt / ethanol / 24 h / Ambient temperature 2: various solvent(s) / 3 h / Heating 3: KOH / methanol / 24 h / Heating 4: 11.3 percent / K3Fe(CN)6, Na2CO3 / H2O / 1) heating, 20 min, 2) r.t., 2 d View Scheme
参考文献
Subramaniam; Gilpin
Synthesis, 1992 , # 12 p. 1232 - 1234
反应条件
T=470.2°C; P=103.2 - 203 Torr; Kinetics; Further Variations:PressuresTemperaturesReagentssurface-to-volume ratio;
参考文献
Chaban, Omar Y.; Dominguez, Rosa M.; Herize, Armando; Tosta, Maria; Cuenca, Angela; Chuchani, Gabriel
Journal of Physical Organic Chemistry, 2007 , vol. 20, # 5 p. 307 - 312
反应条件
sodium hydroxide; water; palladium on activated charcoal T=250°C; 4 h;
参考文献
Matsubara, Seijiro; Yokota, Yutaka; Oshima, Koichiro
Organic Letters, 2004 , vol. 6, # 12 p. 2071 - 2073
反应条件
iron(III) chloride in methyl acetate
3 h; Heating;
参考文献
Womack, Gary B.; Angeles, John G.; Fanelli, Vincent E.; Heyer, Christie A.
Journal of Organic Chemistry, 2007 , vol. 72, # 18 p. 7046 - 7049
反应条件
α,α,α-Trifluoro-p-toluic acid in toluene
T=130°C; 12 h;
参考文献
Cha, Kyung-Mi; Lee, Hyejeong; Park, Jung-Woo; Lee, Yura; Jo, Eun-Ae; Jun, Chul-Ho
Chemistry - An Asian Journal, 2011 , vol. 6, # 8 p. 1926 - 1930
反应条件
1: With lithium diisopropyl amide in tetrahydrofuran
T=-78°C;
2: With manganese(IV) oxide in dichloromethane
Further stages.;
参考文献
Walz, Irene; Bertogg, Andreas; Togni, Antonio
European Journal of Organic Chemistry, 2007 , # 16 p. 2650 - 2658
反应条件
boron trifluoride diethyl etherate
T=-78 - -10°C; 1 h;
参考文献
Naruta, Yoshinori; Nagai, Naoshi; Arita, Yoshihiro; Maruyama, Kazuhiro
Chemistry Letters, 1983 , p. 1683 - 1686
反应条件
1: 98 percent / tetrahydrofuran / 3 h / -78 °C
2: 85 percent / NMO; 4 Angstroem molecular sieves; tetrapropylammonium perruthenate / CH2Cl2 / 3 h / 20 °C
View Scheme
参考文献
Grant, Tina N.; West
Journal of the American Chemical Society, 2006 , vol. 128, # 29 p. 9348 - 9349
反应条件
potassium carbonate; triphenylphosphine; Rhodium trichloride in toluene
Heating;
参考文献
Wang, Zhiyong; Zou, Gang; Tang, Jie
Chemical Communications, 2004 , # 10 p. 1192 - 1193
反应条件
in tetrahydrofuran
T=20°C; 8 h; Product distribution; Further Variations:reaction times;
参考文献
Nudelman; Garcia
Journal of Organic Chemistry, 2001 , vol. 66, # 4 p. 1387 - 1394
