1: coumarin With 1,10-phenanthroline; oxygen; bis(dibenzylideneacetone)-palladium(0) in acetonitrile
Heck type reaction; 0.0833333 h;
2: 3,4,5-trimethoxyphenylboronic acid in N,N-dimethyl-formamide
T=100°C; Heck type reaction; regioselective reaction;
参考文献
Khoobi, Mehdi; Alipour, Masoumeh; Zarei, Samaneh; Jafarpour, Farnaz; Shafiee, Abbas
Chemical Communications, 2012 , vol. 48, # 24 p. 2985 - 2987
1: 68 percent / triethylamine / CH2Cl2 / 8 h / 0 °C
2: 60 percent / HCOOH, triethylamine / triphenylphosphine/Pd(OAc)2 / dimethylformamide / 12 h / 65 °C
View Scheme
参考文献
Donnelly, Dervilla M. X.; Finet, Jean-Pierre; Guiry, Patrick J.; Hutchinson, Rhona M.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1990 , # 10 p. 2851 - 2852
1: 60 percent / pyridine / CHCl3 / 9 h / 40 °C
2: 68 percent / triethylamine / CH2Cl2 / 8 h / 0 °C
3: 60 percent / HCOOH, triethylamine / triphenylphosphine/Pd(OAc)2 / dimethylformamide / 12 h / 65 °C
View Scheme
参考文献
Donnelly, Dervilla M. X.; Finet, Jean-Pierre; Guiry, Patrick J.; Hutchinson, Rhona M.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1990 , # 10 p. 2851 - 2852
1: 60 percent / pyridine / CHCl3 / 9 h / 40 °C
2: 68 percent / triethylamine / CH2Cl2 / 8 h / 0 °C
3: 60 percent / HCOOH, triethylamine / triphenylphosphine/Pd(OAc)2 / dimethylformamide / 12 h / 65 °C
View Scheme
参考文献
Donnelly, Dervilla M. X.; Finet, Jean-Pierre; Guiry, Patrick J.; Hutchinson, Rhona M.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1990 , # 10 p. 2851 - 2852