trifluorormethanesulfonic acid T=80°C; 1 h;

aluminium trichloride; nitrobenzene

暂无反应条件数据

1: sodium hydroxide / water / 2 h / 0 - 20 °C / |Cooling with ice 2: 4-(N,N-dimethlyamino)pyridine; triethylamine / dichloromethane / 0 - 20 °C / |Cooling with ice; |Inert atmosphere 3: lithium chloride; bis-triphenylphosphine-palladium(II) chloride; 2,6-di-tert-butyl-4-methyl-phenol / N,N-dimethyl-formamide / 18 h / 90 °C / |Inert atmosphere View Scheme

1: sodium hydroxide / water / 4 h / 0 °C 2: copper(ll) bromide / ethyl acetate; chloroform; methanol / 4 h / 70 °C 3: 1H-imidazole / dichloromethane / 1.25 h / 20 °C 4: sodium tetrahydroborate / ethanol / 1 h / 20 °C 5: toluene-4-sulfonic acid / toluene / 0.33 h / 80 °C / |Microwave irradiation 6: tetrakis(triphenylphosphine) palladium(0); sodium carbonate / toluene; ethanol; water / 80 °C 7: hydrogen fluoride; pyridine / tetrahydrofuran / 5 h / 20 °C View Scheme

sodium hydroxide in water

1: sodium hydroxide / water / 4 h / 0 °C 2: copper(ll) bromide / ethyl acetate; chloroform; methanol / 4 h / 70 °C 3: 1H-imidazole / dichloromethane / 1.25 h / 20 °C 4: sodium tetrahydroborate / ethanol / 1 h / 20 °C 5: toluene-4-sulfonic acid / toluene / 0.33 h / 80 °C / |Microwave irradiation 6: tetrakis(triphenylphosphine) palladium(0); sodium carbonate / toluene; ethanol; water / 80 °C 7: hydrogen fluoride; pyridine / tetrahydrofuran / 5 h / 20 °C View Scheme

1: 87 percent / NaOH / H2O 2: 42 percent / K2CO3 / acetone / 40 °C 3: 100 percent / H2; ethyl acetate / Pd/C / 12 h / 760 Torr View Scheme

T=100°C;