邻亚二甲苯基联(溴化三苯基膦)合成路线 （共 11 条）
反应条件
in N,N-dimethyl-formamide 3 h; Reflux;
参考文献
Okazaki, Takao; Adachi, Taisuke; Kitagawa, Toshikazu
Bulletin of the Chemical Society of Japan, 2013 , vol. 86, # 4 p. 464 - 471
反应条件
1: NBS, dibenzoyl peroxide / CCl4 / 6 h / Heating 2: dimethylformamide / 8 h / Heating View Scheme
参考文献
Synthesis, , # 6 p. 497 - 498
反应条件
lithium ethanolate in ethanol; N,N-dimethyl-formamide T=90°C; 3 h;
参考文献
Nicolaides, Demetrios D.; Litinas, Konstantinos E.
Journal of Chemical Research, Miniprint, 1983 , # 3 p. 658 - 663
反应条件
lithium ethanolate in ethanol; N,N-dimethyl-formamide T=90°C; 3 h;
参考文献
Nicolaides, Demetrios D.; Litinas, Konstantinos E.
Journal of Chemical Research, Miniprint, 1983 , # 3 p. 658 - 663
反应条件
1: (i) NaOEt, EtOH, (ii) NBS, (PhCO)2O2, AIBN, CCl4 2: acetonitrile 3: (i) nBuLi, THF, Et2O, hexane, (ii) /BRN= 1698469/ 4: Cu(OAc)2 / dimethylformamide 5: KOtBu / 2-methyl-propan-2-ol; benzene View Scheme
参考文献
Staab,H.A. et al.
Chemische Berichte, 1979 , vol. 112, p. 3907 - 3913
反应条件
1: (i) nBuLi, THF, hexane, (ii) /BRN= 1698469/ 2: Cu(OAc)2 / dimethylformamide 3: KOtBu / benzene View Scheme
参考文献
Staab,H.A. et al.
Chemische Berichte, 1979 , vol. 112, p. 3895 - 3906
反应条件
sodium methylate in N,N-dimethyl-formamide T=0 - 20°C; Wittig Olefination; 3.5 h; Inert atmosphere;
参考文献
Okazaki, Takao; Adachi, Taisuke; Kitagawa, Toshikazu
Bulletin of the Chemical Society of Japan, 2013 , vol. 86, # 4 p. 464 - 471
反应条件
lithium ethanolate in N,N-dimethyl-formamide 1.) warming to 90 deg C, 5h; 2.)25 deg C, 12h;
参考文献
Papageorgiou, Georgios; Nicolaides, Demetrios; Stephanidou-Stephanatou, Julia
Liebigs Annalen der Chemie, 1989 , p. 397 - 400
反应条件
lithium hydroxide in dichloromethane 48 h; Ambient temperature;
参考文献
Minsky, Abraham; Rabinovitz, Mordecai
Synthesis, 1983 , # 6 p. 497 - 498
反应条件
lithium ethanolate in ethanol
Ambient temperature;
参考文献
Mitchell,R.H. et al.
Canadian Journal of Chemistry, 1977 , vol. 55, p. 210 - 219
