N-(4-戊炔基)氨基甲酸叔丁酯合成路线 （共 8 条）
反应条件
triethylamine in dichloromethane T=0 - 20°C;
参考文献
WO2013/96771 A1, ;
Page/Page column 215 ;
反应条件
trimethylsilylazide; 1-propanephosphonic acid cyclic anhydride; triethylamine in tetrahydrofuran Curtius rearrangement; Reflux;
参考文献
Synthesis, , # 9 art. no. Z17611SS, p. 1477 - 1483
反应条件
1: LiAlH4 / diethyl ether / 1 h / 23 °C 2: 5.03 g / triethylamine / CH2Cl2 / 0 - 23 °C View Scheme
参考文献
Organic Letters, , vol. 9, # 15 p. 2887 - 2889
反应条件
1.1: hydrazine / ethanol; water / 24 h / 20 °C 1.2: 0.5 h / 20 °C / pH 3 1.3: 0.25 h / 20 °C 2.1: triethylamine / dichloromethane / 20 °C / Ice/water bath View Scheme
反应条件
1: ammonium hydroxide / 80 °C / |Sealed tube 2: triethylamine / dichloromethane / 0 - 20 °C View Scheme
反应条件
1: triethylamine / dichloromethane / 1.5 h / 0 °C 2: ammonium hydroxide / 80 °C / |Sealed tube 3: triethylamine / dichloromethane / 0 - 20 °C View Scheme
反应条件
(THF)W(CO)5 in tetrahydrofuran r.t., 20 h then reflux, 2 d;
参考文献
McDonald, Frank E.; Chatterjee, Arnab K.
Tetrahedron Letters, 1997 , vol. 38, # 44 p. 7687 - 7690
反应条件
C16H26CuO in 2-methyl-propan-1-ol; toluene
T=25°C; 1 h;
参考文献
Whittaker, Aaron M; Lalic, Gojko
Organic Letters, 2013 , vol. 15, # 5 p. 1112 - 1115
