in further solvent(s)
byproducts: H2, CH4, C2H6; a suspension of 9-BBN and Co2(CO)8 in nonane was slowly heated to above90°C (bath temp.) under an inert gas atm.; stirring for about 0.5 h; further products and byproducts; mechanism discussed;; distn. under vac.; mixt. of 9-alkyl-9-BBN obtained, detected by GC/MS;;
Baburajan, Poongavanam; Elango, Kuppanagounder P.
Tetrahedron Letters, 2014 , vol. 55, # 5 p. 1006 - 1010
→
反应条件
in further solvent(s)
Co and Pt complexes were added to oleylamine; mixt. degassed with Ar flow for 20 min under stirring; mixt. heated to 135°C and heated at this temp. for 1 h; heated up to 350°C at a rate of 4°C; refluxed for 1 h; cooled; centrifuged with acetone; washed (hexane/acetone); stored in hexane; identified by X-ray diffraction;
参考文献
Mourdikoudis; Simeonidis; Gloystein; Angelakeris; Dendrinou-Samara; Tsiaoussis; Kalogirou
Journal of Magnetism and Magnetic Materials, 2009 , vol. 321, # 19 p. 3120 - 3125
carbon monoxide; hydrogen; triphenylphosphine in toluene
High Pressure; Ph3P, Co2(CO)8 and toluene subjected to 190°C and 2000 psig of 1:1 H2/CO for 21 h; not isolated; detected by NMR;
参考文献
Dubois, Robert A.; Garrou, Philip E.; Lavin, Karen D.; Allcock, Harry R.
Organometallics, 1986 , vol. 5, p. 460 - 466
