hydrogenchloride in diethyl ether; n-heptane Kinetics; byproducts: CO; addn. of Co complex soln. (n-heptane) to stirred soln. of dry HCl in diethyl ether under CO (atmospheric pressure), 25°C; rapid gas evolution and pptn.; detn. by IR and evapn.;
in tetrahydrofuran The iron complex and Co(CO)8 are slurried in THF under CO (20 min).; Evapn., resulting oil is dissolved in Et2O, (PPN)Co(CO)4 is removed by filtration, addn. of 2-propanol, evapn. yields black/purple PPN-compound which is washed with pentane and dried by vac, elem. anal.;
参考文献
Ching, Stanton; Holt, Elizabeth M.; Kolis, Joseph W.; Shriver, Duward F.
Organometallics, 1988 , vol. 7, p. 892 - 898
