顺-二氯二(吡啶)铂(II)合成路线 （共 34 条）
反应条件
in not given effect of NaCl-soln.;;
参考文献
Journal of the Chemical Society, , p. 988 - 1004
Pt: MVol.D, 125, page 283 - 285
反应条件
in not given heating with pyridine for several days on a water-bath;;
参考文献
Journal of the Chemical Society, , p. 2216 - 2221
Pt: MVol.D, 129, page 290 - 292
反应条件
in pyridine reaction in boiling pyridine;;
参考文献
Journal of the Chemical Society, , p. 2216 - 2221
Pt: MVol.D, 129, page 290 - 292
反应条件
in acetone Kinetics; Pt-complex:pyridine molar ratio was 1:10, 20 °C, 32 h, 100 percent conversion; monitored by (1)H NMR, mixt. was extd. with water, water was evapd., residue was washed with CH2Cl2, isolated yield of Ptpy4Cl2 was 43 percent;
参考文献
Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, , vol. 27, # 8 p. 579 - 584
反应条件
in dimethyl sulfoxide Kinetics; byproducts: C5H5N; placing soln. of cis-(PtCl2(C5H5N)2) in Me2SO in NMR-tube; not isolated, detected by NMR;
参考文献
Fontes; Oskarsson; Loevqvist; Farrell
Inorganic Chemistry, 2001 , vol. 40, # 8 p. 1745 - 1750
反应条件
in dimethyl sulfoxide dissolving of cis-Pt(Py)2Cl2 in dimethylsulfoxide in flask equipped witha refluxer; heating at 80°C for 14 h; cooling; addn. of H2O or Et2O; pptn., filtration, monitoring by NMR; as mixt. of cis- and trans-isomers;
参考文献
De Vekki
Russian Journal of Inorganic Chemistry, 2008 , vol. 53, # 8 p. 1238 - 1241
反应条件
in dimethyl sulfoxide dissolving of cis-Pt(Py)2Cl2 in dimethylsulfoxide in flask equipped witha refluxer; heating at 80°C for 16 h; cooling; addn. of H2O or Et2O; pptn., filtration, monitoring by NMR; as mixt. of cis- and trans-isomers;
参考文献
De Vekki
Russian Journal of Inorganic Chemistry, 2008 , vol. 53, # 8 p. 1238 - 1241
反应条件
1: ammonia 2: HCl / hydrogenchloride View Scheme
参考文献
Gmelin Handbook: Pt: MVol.D, 125, page 283 - 285
反应条件
in further solvent(s) dissolving of cis-Pt(Py)2Cl2 in diethylsulfoxide in flask equipped with a refluxer; heating at 80°C for 14 h; cooling; addn. of H2O or Et2O; pptn., filtration, monitoring by NMR;
参考文献
De Vekki
Russian Journal of Inorganic Chemistry, 2008 , vol. 53, # 8 p. 1238 - 1241
反应条件
in further solvent(s) dissolving of cis-Pt(Py)2Cl2 in diethylsulfoxide in flask equipped with a refluxer; heating at 80°C for 14 h; further exposure of reaction mixt.; cooling; addn. of H2O or Et2O; pptn., filtration, monitoring by NMR; as mixt. of cis- and trans-isomers;
参考文献
De Vekki
Russian Journal of Inorganic Chemistry, 2008 , vol. 53, # 8 p. 1238 - 1241
