1-氟-3-苯基丙烷-2-酮合成路线 (共 5 条)
反应条件
T=508°C; P=0.1 Torr;
参考文献
Reutrakul, Vichai; Kruahong, Thongchai; Pohmaktor, Manat
Tetrahedron Letters, 1994 , vol. 35, # 27 p. 4851 - 4852
反应条件
in diethyl ether T=-60°C;
参考文献
Kitazume,T.; Asai,M.; Lin,J.T.
Journal of Fluorine Chemistry, 1987 , vol. 35, p. 477
反应条件
1: 91 percent / LDA / tetrahydrofuran; hexamethylphosphoric acid triamide / 2 h / -78 °C 2: 45 percent / 508 °C / 0.1 Torr View Scheme
参考文献
Reutrakul, Vichai; Kruahong, Thongchai; Pohmaktor, Manat
Tetrahedron Letters, 1994 , vol. 35, # 27 p. 4851 - 4852
反应条件
1: 1.) 3-chloroperbenzoic acid, 2.) KF / 1.) CHCl3, 25 deg C, 24 h, 2.) CHCl3, 5 h 2: 65 percent / Et3N*3HF / 2 h / 125 °C View Scheme
参考文献
Michel; Schlosser
Tetrahedron, 1996 , vol. 52, # 7 p. 2429 - 2434
反应条件
sodium tetrahydroborate in ethanol
Ambient temperature;
参考文献
Kitazume,T.; Asai,M.; Lin,J.T.
Journal of Fluorine Chemistry, 1987 , vol. 35, p. 477