1,1,1-三氟丁烯-3合成路线 （共 25 条）
反应条件
1: tetrahydrofuran-2-one With potassium hydroxide in water T=50 - 140°C; P=150.015 - 760.051 Torr; 2: 1,1,1-trifluoro-4-iodobutane in water T=75 - 140°C; 7 h; Product distribution / selectivity;
参考文献
Tosoh F-Tech, Inc.
Patent: EP1403238 A1, 2004 ;
Location in patent: Page 4 ;
反应条件
potassium hydroxide; water in gamma-butyro-lactone T=90 - 100°C; 18.8 h; Product distribution / selectivity;
参考文献
Tosoh Corporation; Tosoh F-Tech Inc.
Patent: JP2005/187423 A, 2005 ;
Location in patent: Page/Page column 6 ;
反应条件
sodium hydroxide in water T=90°C; 36 h; Product distribution / selectivity;
参考文献
Tosoh F-Tech, Inc.
Patent: EP1403238 A1, 2004 ;
Location in patent: Page 5 ;
反应条件
T=246.9 - 306.9°C; P=300 Torr; Further byproducts given;
参考文献
Haszeldine, Robert N.; Keen, David W.; Robinson, Peter J.
Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1983 , # 11 p. 1713 - 1718
反应条件
in N,N-dimethyl-formamide Ambient temperature;
参考文献
Wiemers, Denise M.; Burton, Donald J.
Journal of the American Chemical Society, 1986 , vol. 108, # 4 p. 832 - 834
反应条件
15-crown-5; cesium fluoride in ethylene glycol dimethyl ether T=-18 - 20°C; 1 h;
参考文献
Tyrra, Wieland; Naumann, Dieter; Quadt, Silke; Buslei, Sigrid; Yagupolskii, Yurii L.; Kremlev, Mikhail M.
Journal of Fluorine Chemistry, 2007 , vol. 128, # 7 p. 813 - 817
反应条件
tetrakis(triphenylphosphine) palladium(0) in benzene 3 h; Ambient temperature;
参考文献
Matsubara, Seijiro; Mitani, Makoto; Utimoto, Kiitiro
Tetrahedron Letters, 1987 , vol. 28, # 47 p. 5857 - 5860
反应条件
ethanol; potassium acetate
参考文献
Eastman Kodak Co.
Patent: US2700686 , 1951 ;
Full Text Show Details
Eastman Kodak Co.
Patent: US2768160 , 1951 ;
参考文献
Haszeldine et al.
Journal of the Chemical Society, 1954 , p. 2040
反应条件
hydrogenchloride; magnesium; zinc
参考文献
Haszeldine et al.
Journal of the Chemical Society, 1954 , p. 2040
