O-(三甲基硅烷基)苯酚合成路线 （共 28 条）
反应条件
n-butyllithium in diethyl ether; hexane
T=20°C; 0.0166667 h; Flow reactor; Temperature;
参考文献
Michel, Boris; Greaney, Michael F.
Organic Letters, 2014 , vol. 16, # 10 p. 2684 - 2687
反应条件
hydrogenchloride; n-butyllithium; triethylamine in tetrahydrofuran; chloro-trimethyl-silane; hexane; water
参考文献
Eastman Kodak Company
Patent: US5359065 A1, 1994 ;
反应条件
1: With azobisisobutyronitrile; tri-n-butyl-tin hydride in benzene
Rearrangement; 7.5 h;
2: With methyllithium in benzene
T=20°C; desilylation; 12 h; Further stages.;
参考文献
Studer, Armido; Bossart, Martin; Vasella, Tomaso
Organic Letters, 2000 , vol. 2, # 7 p. 985 - 988
反应条件
1: ortho-bromo-phenol With n-butyllithium in tetrahydrofuran; hexane
T=-78°C;
2: chloro-trimethyl-silane in tetrahydrofuran; hexane
3: With tetrabutyl ammonium fluoride in tetrahydrofuran; hexane
参考文献
Nishide, Kiyoharu; Ohsugi, Shin-Ichi; Miyamoto, Tetsuo; Kumar, Kamal; Node, Manabu
Monatshefte fur Chemie, 2004 , vol. 135, # 2 p. 189 - 200
反应条件
1.1: 84 percent / triethylamine / DMAP / tetrahydrofuran / 0 - 20 °C
2.1: Bu3SnH; α,α'-azobis(isobutyronitrile) / benzene / 7.5 h
2.2: 50 percent / methyllithium / benzene / 12 h / 20 °C
View Scheme
参考文献
Studer, Armido; Bossart, Martin; Vasella, Tomaso
Organic Letters, 2000 , vol. 2, # 7 p. 985 - 988
反应条件
1.1: 71 percent / Bu3SnH; α,α'-azobis(isobutyronitrile); methyllithium / benzene
2.1: 84 percent / triethylamine / DMAP / tetrahydrofuran / 0 - 20 °C
3.1: Bu3SnH; α,α'-azobis(isobutyronitrile) / benzene / 7.5 h
3.2: 50 percent / methyllithium / benzene / 12 h / 20 °C
View Scheme
参考文献
Studer, Armido; Bossart, Martin; Vasella, Tomaso
Organic Letters, 2000 , vol. 2, # 7 p. 985 - 988
反应条件
2-butyl furan; sodium hydroxide in acetonitrile
T=20°C; 5 h; Inert atmosphere;
参考文献
Ikawa, Takashi; Nishiyama, Tsuyoshi; Nosaki, Toshifumi; Takagi, Akira; Akai, Shuji
Organic Letters, 2011 , vol. 13, # 7 p. 1730 - 1733
反应条件
2-butyl furan; sodium hydroxide in acetonitrile
T=20°C; 5 h; Inert atmosphere;
参考文献
Ikawa, Takashi; Nishiyama, Tsuyoshi; Nosaki, Toshifumi; Takagi, Akira; Akai, Shuji
Organic Letters, 2011 , vol. 13, # 7 p. 1730 - 1733
参考文献
Gilman, H.; Nobis, J. F.
Journal of the American Chemical Society, 1950 , vol. 72, p. 2629 - 2632
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Speier, J. L.
Journal of the American Chemical Society, 1952 , vol. 74, p. 1003 - 1010
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Gmelin Handbook: Si: MVol.C, 22, page 68 - 71
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Dow Corning Corp.
Patent: US2611777 , 1952 ;
C. A., 1953 , p. 4127
反应条件
tri-iso-propyl phosphine; (η3-allyl)(η5-Cp)Pd in toluene
T=110°C; 15 h; Yield given. Yields of byproduct given;
参考文献
Binger, Paul; Sternberg, Ethan; Wittig, Ute
Chemische Berichte, 1987 , vol. 120, p. 1933 - 1938
