in tetrahydrofuran
a mixt. of Br2C(COOMe)2 and Rh-complex in 1:1 molar ratio was heated inTHF at 50°C for 5 h under N2; solvent was removed, residue extd. with hexane to give (MeOOC)2C=C(COOMe)2, extraction residue was chromd. to give RhBr3(CO)(PPh3)2;
参考文献
Booth, Brian L.; Casey, Geoffrey C.; Haszeldine, Robert N.
Journal of Organometallic Chemistry, 1982 , vol. 224, # 2 p. 197 - 205
NSCl*C4H8O in not given
soln. of Rh-complex in THF or CH2Cl2 was treated with 1 equiv of soln. of NSCl*THF in THF, stirred for ca. 1 h;
参考文献
Hursthouse, Michael B.; Walker, Nigel P. C.; Warrens, Christopher P.; Woollins, J. Derek
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1985 , p. 1043 - 1048
in dichloromethane byproducts: CO; Irradiation (UV/VIS); flash photolysis: photolysis of metal complex in deaerated CH2Cl2 at 23+/-2°C (λ >315 nm) under Ar; not isolated, detd. by NMR;
参考文献
Wink, David A.; Ford, Peter C. Journal of the American Chemical Society, 1987 , vol. 109, # 2 p. 436 - 442
With hydrogen in benzene Kinetics; byproducts: CO; Irradiation (UV/VIS); flash photolysis: photolysis of metal complex in deaerated C6H6 under H2 at 23+/-2°C (λ >315 nm); reversible process; not isolated, detd. by NMR;
参考文献
Wink, David A.; Ford, Peter C. Journal of the American Chemical Society, 1987 , vol. 109, # 2 p. 436 - 442
