反应条件
1: 80 percent / phosphoryl chloride / CHCl3 / 2 h / Heating 2: 1.) tetrakis(triphenylphosphine)palladium<0>, 2.) 2 M aq. Na2CO3 / 1.) DME, 10 min, 2.) DME, EtOH, reflux, overnight 3: 86 percent / BBr3 / CH2Cl2 / Heating 4: 84 percent / DMAP / CH2Cl2 5: 60 percent / 1,3-bis(diphenylphosphino)propane, palladium acetate, NaHCO3 / dimethylsulfoxide / 20 h / 85 °C 6: 84 percent / trichlorosilane, Et3N / toluene / 2 h / Heating View Scheme
参考文献
Alcock, Nathaniel W.; Brown, John M.; Hulmes, David I.
Tetrahedron: Asymmetry, 1993 , vol. 4, # 4 p. 743 - 756
