(S)-(+)-对甲苯sulfinamide n-亚苄基合成路线 （共 6 条）
反应条件
1: (SS)-(-)-L-Menthyl toluene-p-sulfinate With lithium hexamethyldisilazane in tetrahydrofuran T=-78 - 20°C; 5 h; Inert atmosphere; 2: benzaldehyde in tetrahydrofuran T=-78°C; 2 h; Inert atmosphere;
参考文献
Blangetti, Marco; Croce, Gianluca; Deagostino, Annamaria; Mussano, Eleonora; Prandi, Cristina; Venturello, Paolo
Journal of Organic Chemistry, 2011 , vol. 76, # 6 p. 1814 - 1820
反应条件
pyrrolidine in dichloromethane T=60°C; 1 h; Molecular sieve;
参考文献
Morales, Sara; Guijarro, Fernando G.; Garcia Ruano, Jose Luis; Cid, M. Belen
Journal of the American Chemical Society, 2014 , vol. 136, # 3 p. 1082 - 1089
反应条件
titanium tetraethoxide T=70°C; 1 h; Neat (no solvent)Microwave irradiationInert atmosphere;
参考文献
Collados, Juan F.; Toledano, Estefania; Guijarro, David; Yus, Miguel
Journal of Organic Chemistry, 2012 , vol. 77, # 13 p. 5744 - 5750
反应条件
1: chloro-trimethyl-silane / diethyl ether / 18 h / 20 °C / |Inert atmosphere 2: dichloromethane-d2 / 20 °C / |Inert atmosphere View Scheme
参考文献
Morales, Sara; Guijarro, Fernando G.; Garcia Ruano, Jose Luis; Cid, M. Belen
Journal of the American Chemical Society, 2014 , vol. 136, # 3 p. 1082 - 1089
反应条件
in dichloromethane-d2 T=20°C; Inert atmosphere;
参考文献
Morales, Sara; Guijarro, Fernando G.; Garcia Ruano, Jose Luis; Cid, M. Belen
Journal of the American Chemical Society, 2014 , vol. 136, # 3 p. 1082 - 1089
反应条件
1: (1R,2S,5R)-(-)-menthyl (S)-p-toluenesulfinate With lithium hexamethyldisilazane 2: benzaldehyde
参考文献
Sun, Wangsheng; Ma, Xiaozhou; Hong, Liang; Wang, Rui
Journal of Organic Chemistry, 2011 , vol. 76, # 19 p. 7826 - 7833
