N-(2-氯丙-2-烯基)苯胺合成路线 （共 12 条）
反应条件
in water T=50 - 65°C; 4.5 h;
参考文献
Barluenga, Jose; Foubelo, Francisco; Fananas, Francisco J.; Yus, Miguel
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1989 , p. 553 - 557
反应条件
potassium fluoride in acetonitrile 6 h; Heating;
参考文献
Pace, Vittorio; Martinez, Fernando; Fernandez, Maria; Sinisterra, Jose V.; Alcantara, Andres R.
Organic Letters, 2007 , vol. 9, # 14 p. 2661 - 2664
反应条件
potassium carbonate in dimethyl sulfoxide T=85 - 95°C; 5 h; Yields of byproduct given;
参考文献
Nazarov; Magerramov
Russian Journal of Organic Chemistry, 1997 , vol. 33, # 1 p. 66 - 67
反应条件
tricyclo[3.3.1.13,7 ]-decane-1-carboxylic acid; triphenylphosphine; bis(acetylacetonato) palladium in water 0.5 h; Heating;
参考文献
Yang, Shyh-Chyun; Hsu, Yi-Chun; Gan, Kim-Hong
Tetrahedron, 2006 , vol. 62, # 17 p. 3949 - 3958
反应条件
potassium carbonate in dimethyl sulfoxide T=95 - 105°C; 4 h; dependence of the yield on the conditions of the reaction;
参考文献
Nazarov; Magerramov
Russian Journal of Organic Chemistry, 1997 , vol. 33, # 1 p. 66 - 67
反应条件
potassium carbonate in acetone Heating;
参考文献
Anderson,W.K. et al.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1976 , p. 1 - 4
反应条件
1: 88 percent / triethylamine / hexane / ice-water bath, then room temperature, 1 h 2: 54 percent / conc H2SO4 / 2 h 3: polyphosphoric acid / 0.67 h / 120 °C 4: KOH / methanol / 0.67 h / 120 °C View Scheme
参考文献
Nordlander, J. Eric; Catalane, David B.; Kotian, Kirtivan D.; Stevens, Randall M.; Haky, Jerome E.
Journal of Organic Chemistry, 1981 , vol. 46, p. 778 - 782
反应条件
hydrogen fluoride T=200°C;
参考文献
Eastman Kodak Co.
Patent: US2607779 , 1950 ;
反应条件
1: 1.) phenyl-lithium, 2.) lithium naphthalenide / 1.) diethyl ether, THF, -78 deg C, 30 min, 2.) -78 deg C, 2 h 2: 93 percent / H2O / diethyl ether; tetrahydrofuran / Ambient temperature; reactions with other electrophiles View Scheme
参考文献
Barluenga, Jose; Foubelo, Francisco; Fananas, Francisco J.; Yus, Miguel
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1989 , p. 553 - 557
反应条件
1.1: n-butyllithium / tetrahydrofuran; hexane / -78 - 20 °C
1.2: 50 percent / tetrahydrofuran; hexane / -78 - 20 °C
2.1: 11 percent Spectr. / Et3Al; FeCl3; DPEPhos / toluene
View Scheme
参考文献
Necas, David; Kotora, Martin; Cisarova, Ivana
European Journal of Organic Chemistry, 2004 , # 6 p. 1280 - 1285
