1: 41.5 percent / NaAlH2(OCH2CH2OCH3)2 / toluene / 20 h / Heating 2: 90.2 percent / NaNH2 / xylene / 1.5 h / 130 °C View Scheme

sodium bis(2-methoxyethoxy)aluminium dihydride in toluene 20 h; Heating;

&nbsp;<b>in</b>&nbsp; <a href="#" onclick="return RXDsubstances(event, this, '606078', constants.ctx, '0')">1,2-dichloro-benzene</a> <br />T=190&deg;C;&nbsp;0.25&nbsp;h;&nbsp;<br /> &nbsp;

<b>Multi-step reaction with 4 steps<br /> </b>1: 100 percent / n-BuLi / tetrahydrofuran; hexane / 1.) r.t., 30 min, 2.) r.t., 12 h<br />2: 93.5 percent / n-BuLi / diethyl ether; hexane / 1.) -78 deg C, 1 h, 2.) r.t., 12 h<br />3: 98 percent / diphenyl phosphorazidate, Et₃N / benzene / 1 h / 50 &deg;C<br />4: 86.4 percent / 1,2-dichloro-benzene / 0.25 h / 190 &deg;C<br /> <br /> &nbsp;