1: With 4,4'-methylene-bis-(2,6-diphenylphenol); triethylaluminum in toluene T=25°C; 1 h; 2: 3,7-dimethyloct-6-en-1-al With acetic anhydride in toluene T=0°C; 1 - 72 h; Product distribution / selectivity;
bis(bicyclo[2.2.1]hepta-2,5-diene)dichlorodirhodium; tributylphosphine; hydrogen in methanol; benzene T=50°C; 6 h; also in the presence of Et3N + PPh3; Rate constant;
参考文献
Journal of Organometallic Chemistry, , vol. 255, # 3 p. 377 - 384
1: With 4,4'-lt;2,2,2-trifluorethylidenegt;-bis-2,6-diphenyl-phenol; triethylaluminum in toluene T=25°C; 1 h; 2: 3,7-dimethyloct-6-en-1-al With acetic anhydride in toluene T=0°C; 1 - 72 h; Product distribution / selectivity;