1-[(5alpha,7alpha)-4,5-环氧-3,6-二甲氧基-17-甲基-6,14-乙烯桥吗喃-7-基]乙酮合成路线 （共 5 条）
反应条件
1.1: palladium 10 on activated carbon; hydrogen / methanol / 3102.97 Torr 2.1: magnesium / diethyl ether / Inert atmosphere; Reflux 2.2: 20 °C 3.1: potassium carbonate; thiophenol / 1-methyl-pyrrolidin-2-one / 0.5 h / 220 - 230 °C / Inert atmosphere View Scheme
参考文献
Huang, Xin-Ren; Srimurugan, Sankareswaran; Lee, Gene-Hsiang; Chena, Chinpiao
Journal of the Chinese Chemical Society, 2011 , vol. 58, # 1 p. 101 - 107
反应条件
1: (catalytic hydrogenation) 4: (i) KOH, (ii) /BRN= 605296/, NaHCO3, DMF View Scheme
参考文献
Carroll,F.I. et al.
Journal of Organic Chemistry, 1976 , vol. 41, # 6 p. 996 - 1001
反应条件
1: 73.2 percent / diethyl ether; tetrahydrofuran / heating 2: 75.4 percent / EtSNa / dimethylformamide / heating View Scheme
参考文献
Fulmor; Lancaster; Morton; Brown; Howell; Nora; Hardy Jr.
Journal of the American Chemical Society, 1967 , vol. 89, # 13 p. 3322 - 3330
参考文献
Bentley; Hardy; Meek
Journal of the American Chemical Society, 1967 , vol. 89, # 13 p. 3273 - 3280
参考文献
Bentley; Hardy; Meek
Journal of the American Chemical Society, 1967 , vol. 89, # 13 p. 3273 - 3280
