1: sec-butylmagnesium chloride With zinc(II) chloride in tetrahydrofuran
T=20°C; 0.333333 h;
2: ortho-chlorotoluene With Pd0(tris(tert-butyl)phosphine)2 in tetrahydrofuran; 1-methyl-pyrrolidin-2-one
T=100°C; Negishi reaction; 24 h; Further stages. Title compound not separated from byproducts.;
参考文献
Dai; Fu
Journal of the American Chemical Society, 2001 , vol. 123, # 12 p. 2719 - 2724
NiCl2((PPh3)P)2 in diethyl ether
20 h; Ambient temperature;
参考文献
Hayashi, Tamio; Konishi, Mitsuo; Kobori, Yuji; Kumada, Makoto; Higuchi, Taiichi; Hirotsu, Ken
Journal of the American Chemical Society, 1984 , vol. 106, p. 158 - 163
