暂无反应条件数据

1: With sulfuric acid; sodium nitrite T=0 - 20°C; 17 h; 2: With potassium iodide in water Further stages.;

1.1: 121 g / (MeO)3B; BH3*Me2S / tetrahydrofuran / 18 h / 20 °C 2.1: PPh3; Br2 / acetonitrile / 1 h / 20 °C 3.1: LDA; t-BuOMe / various solvent(s); tetrahydrofuran / -30 - 0 °C 4.1: NaH / dimethylformamide / 1 h / 0 °C 4.2: 10 g / dimethylformamide / 0.25 h / 0 °C 5.1: 91 percent / n-BuLi / tetrahydrofuran; cyclohexane / 0.17 h / -78 °C View Scheme

in water Heating;

boric acid trimethyl ester; dimethylsulfide borane complex in tetrahydrofuran T=20°C; 18 h;

1: 78 percent / K2CO3, CuCl / dimethylformamide / 4 h / 140 °C 2: 87 percent / LiAlH4 / diethyl ether / 2.5 h / Heating 3: 96 percent / SOCl2 / benzene / 1.) 25 deg C, 20 min 2.) 60 deg C, 1 h 3.) reflux 1.5 h 4: KI / acetone / 5 h / Heating 5: LiAlH4 / diethyl ether / 2.5 h / Heating View Scheme

1: 78 percent / K2CO3, CuCl / dimethylformamide / 4 h / 140 °C 2: 87 percent / LiAlH4 / diethyl ether / 2.5 h / Heating 3: 96 percent / SOCl2 / benzene / 1.) 25 deg C, 20 min 2.) 60 deg C, 1 h 3.) reflux 1.5 h 4: 50 percent / dimethylformamide / 2 h / 35 °C 5: 98 percent / KOH / ethanol; H2O / 3 h / Heating View Scheme