3-乙基-2,4-戊二酮合成路线 （共 26 条）
反应条件
sodium acetate; acetic acid; zinc
参考文献
Kleinspehn
Journal of the American Chemical Society, 1955 , vol. 77, p. 1546
反应条件
acetic acid; zinc 1 h; Heating;
参考文献
Berezin, M. V.; Semeikin, A. S.; V'yugin, A. I.; Krestov, G. A.
Russian Chemical Bulletin, 1993 , vol. 42, # 3 p. 449 - 453
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1993 , # 3 p. 495 - 499
反应条件
1: 39 percent / glacial HOAc, Zn dust, NaOAc / 2 h / 85 °C
2: 56 percent / Pb(OAc)4, glacial HOAc
3: 40 percent / aq. HCl / ethanol / 1 h / Heating
4: 86 percent / H2 / 10percent Pd/C / ethyl acetate / 21 h / Ambient temperature
View Scheme
参考文献
Helms, Anna; Heiler, David; McLendon, George
Journal of the American Chemical Society, 1992 , vol. 114, # 15 p. 6227 - 6238
反应条件
1: 60 percent / Zn, AcOH / 1 h / Heating
2: 80 percent / KOH / ethane-1,2-diol / 5 h / Heating
3: 75 percent / POCl3 / 2 h / 20 °C
View Scheme
参考文献
Berezin, M. V.; Semeikin, A. S.; V'yugin, A. I.; Krestov, G. A.
Russian Chemical Bulletin, 1993 , vol. 42, # 3 p. 449 - 453
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1993 , # 3 p. 495 - 499
反应条件
1: zinc / acetic acid / 1 h / Heating
2: 1.) sulfuryl chloride, 2.) sodium acetate / 1.) ether, room temp., 12 h, 2.) acetone, water, reflux, 2 h
View Scheme
参考文献
Mamardashvili, N. Zh.; Semeikin, A. S.; Golubchikov, O. A.
Russian Journal of Organic Chemistry, 1993 , vol. 29, # 6.2 p. 1007 - 1015
Zhurnal Organicheskoi Khimii, 1993 , vol. 29, # 6 p. 1213 - 1223
反应条件
potassium carbonate in acetone
Heating;
参考文献
Kalaitzakis, Dimitris; Rozzell, J. David; Smonou, Ioulia; Kambourakis, Spiros
Advanced Synthesis and Catalysis, 2006 , vol. 348, # 14 p. 1958 - 1969
