(R)-(+)-环氧丙烷合成路线 （共 61 条）
反应条件
air; 4-nitro-benzoic acid; (R,R)-((t-Bu)4-salen)Co(II) in various solvent(s) T=20°C; 24 h;
参考文献
Bartoli, Giuseppe; Bosco, Marcella; Carlone, Armando; Locatelli, Manuela; Melchiorre, Paolo; Sambri, Letizia
Organic Letters, 2004 , vol. 6, # 22 p. 3973 - 3975
反应条件
bis(triphenylphosphine)iminium acetate; C64H74Cl2Co2N4O4 in toluene T=0°C; 1.5 h; Resolution of racemateInert atmosphere; optical yield given as percent ee;
参考文献
Hirahata, Wataru; Thomas, Renee M.; Lobkovsky, Emil B.; Coates, Geoffrey W.
Journal of the American Chemical Society, 2008 , vol. 130, # 52 p. 17658 - 17659
反应条件
dihydrogen peroxide; [(S,S-(C6H5)2PCH(CH3)CH(CH3)P(C6H5)2)Pt(pentafluorophenyl)(OH2)]CF3SO3) in dichloromethane T=-25°C; 24 h; Title compound not separated from byproducts;
参考文献
Journal of the American Chemical Society, , vol. 128, # 43 p. 14006 - 14007
反应条件
[(R,R)-N,N'-bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminato(2-)]cobalt(III) acetate; water T=0 - 20°C; 12 h;
参考文献
Journal of the American Chemical Society, , vol. 124, # 7 p. 1307 - 1315
反应条件
potassium hydroxide in water T=70 - 80°C;
参考文献
Mori, Kenji; Senda, Shuji
Tetrahedron, 1985 , vol. 41, # 3 p. 541 - 546
反应条件
(S,S)-[1,2-cyclohexanediamino-N,N'-bis(3,5-di-t-butylsalicylidene)]cobaltIII*OAc; water T=0 - 20°C;
参考文献
Schaus, Scott E.; Brandes, Bridget D.; Larrow, Jay F.; Tokunaga, Makoto; Hansen, Karl B.; Gould, Alexandra E.; Furrow, Michael E.; Jacobsen, Eric N.
Journal of the American Chemical Society, 2002 , vol. 124, # 7 p. 1307 - 1315
反应条件
potassium hydroxide; (R,R)-[Co(salen)]2*GaCl3 in 1,4-dioxane
参考文献
Thakur, Santosh Singh; Chen, Shu-Wei; Li, Wenji; Shin, Chang-Kyo; Kim, Seong-Jin; Koo, Yoon-Mo; Kim, Geon-Joong
Journal of Organometallic Chemistry, 2006 , vol. 691, # 9 p. 1862 - 1872
反应条件
4-(dimethylamino)quinoline; chiral salen Co(III) complex p-toluenesulfonate T=20°C; P=7757.43 Torr; 4.5 h;
参考文献
Macromolecules, , vol. 38, # 15 p. 6251 - 6253
反应条件
C64H74Cl2Co2N4O4; bis(triphenylphosphoranylidene)-ammonium acetate in toluene T=0°C; 0.25 h; Product distribution / selectivity;
参考文献
CORNELL RESEARCH FOUNDATION, INC.
Patent: WO2009/26261 A2, 2009 ;
Location in patent: Page/Page column 68-69 ;
反应条件
sodium nitroferricyanide (III); potassium carbonate in water T=15 - 20°C; 2 h;
参考文献
Rossen; Simpson; Wells
Synthetic Communications, 1993 , vol. 23, # 8 p. 1071 - 1074
