(R)-(+)-环氧丙烷合成路线 (共 61 条)
反应条件
potassium pentaoxide in pentan-1-ol
参考文献
Lee, Linda G.; Whitesides, George M.
Journal of Organic Chemistry, 1986 , vol. 51, # 1 p. 25 - 36
反应条件
water; chiral ((substituted salen)Co)2-InCl3 T=20°C; 2 h;
参考文献
Thakur, Santosh Singh; Chen, Shu-Wei; Li, Wenji; Shin, Chang-Kyo; Koo, Yoon-Mo; Kim, Geon-Joong
Synthetic Communications, 2006 , vol. 36, # 16 p. 2371 - 2383
反应条件
air; 4-nitro-benzoic acid in various solvent(s) T=20°C; 18 h; Title compound not separated from byproducts;
参考文献
Organic Letters, , vol. 7, # 10 p. 1983 - 1985
反应条件
hydrogenchloride; (R,R)-[Co(salen)]*GaCl3 in diethyl ether T=0 - 4°C; 1 h;
参考文献
Journal of Organometallic Chemistry, , vol. 691, # 9 p. 1862 - 1872
反应条件
pyridine; sodium hydroxide; borane; p-toluenesulfonyl chloride 2.) THF; Yield given. Multistep reaction;
参考文献
Journal of the American Chemical Society, , vol. 107, # 19 p. 5556 - 5558
反应条件
(1R,2R)-(t-Bu)2salenCoIII(OCOCF3) in chloroform T=10°C; 18 h; Title compound not separated from byproducts;
参考文献
Organic Letters, , vol. 8, # 20 p. 4401 - 4404
反应条件
PTAT; salen-type BINOL-based Co(III) chiral catalyst T=25°C; P=3750.38 Torr; 100 h;
参考文献
Tetrahedron Asymmetry, , vol. 19, # 16 p. 1947 - 1953
反应条件
potassium hydroxide in water 1.) 70 deg C; 2.) 90 deg C; Yield given;
参考文献
Journal of Organic Chemistry, , vol. 46, # 16 p. 3348 - 3349
反应条件
lithium aluminium tetrahydride; Diethyloxytriphenylphosphorane 2.) CH2Cl2, 90 h, reflux; Yield given. Multistep reaction;
参考文献
Journal of the American Chemical Society, , vol. 107, # 18 p. 5210 - 5219
反应条件
sodium methylate in methanol Ambient temperaturee.e. 96percent; Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Tetrahedron Letters, , vol. 26, # 41 p. 5037 - 5040