(R)-(+)-环氧丙烷合成路线 （共 61 条）
反应条件
copper(l) iodide in tetrahydrofuran T=0°C;
参考文献
Merlo; Gallardo
Synthetic Communications, 1993 , vol. 23, # 15 p. 2159 - 2169
反应条件
monofluoromethane T=25°C; P=720 Torr; Irradiationalso in the presence of H2O or CH4; Product distributionMechanism;
参考文献
Troiani, Anna; Filippi, Antonello; Speranza, Maurizio
Chemistry - A European Journal, 1997 , vol. 3, # 12 p. 2063 - 2070
反应条件
1: bromobenzene With magnesium in tetrahydrofuran T=0°C; 1 h; Inert atmosphere; 2: With copper (I) cyanide in tetrahydrofuran T=-35°C; 0.5 h; 3: (R)-(+)-propylene oxide in tetrahydrofuran T=-35 - 20°C; 1.5 h;
参考文献
Taguri, Tomonori; Yamamoto, Masanobu; Fujii, Toru; Muraki, Yuta; Ando, Tetsu
European Journal of Organic Chemistry, 2013 , # 30 p. 6924 - 6933
反应条件
in water T=0 - 20°C;
参考文献
MERCK and CO., INC.
Patent: WO2004/92124 A2, 2004 ;
Location in patent: Page 71 ;
WO 2004/092124 A2
反应条件
hydrogenchloride in carbon disulfide
参考文献
Nakajima,T. et al.
Bulletin of the Chemical Society of Japan, 1967 , vol. 40, p. 2980
反应条件
monofluoromethane T=25°C; P=720 Torr; Irradiationalso in the presence of H2O or CH4; Product distributionMechanism;
参考文献
Troiani, Anna; Filippi, Antonello; Speranza, Maurizio
Chemistry - A European Journal, 1997 , vol. 3, # 12 p. 2063 - 2070
反应条件
aluminium trichloride in carbon disulfide; benzene
参考文献
Nakajima,T. et al.
Bulletin of the Chemical Society of Japan, 1967 , vol. 40, p. 2980
反应条件
methylmagnesium bromide; copper (I) cyanide in tetrahydrofuran; diethyl ether T=-35 - 20°C; 1.5 h; Inert atmosphere;
参考文献
Taguri, Tomonori; Yamamoto, Masanobu; Fujii, Toru; Muraki, Yuta; Ando, Tetsu
European Journal of Organic Chemistry, 2013 , # 30 p. 6924 - 6933
反应条件
hydrogen bromide in carbon disulfide
参考文献
Nakajima,T. et al.
Tetrahedron, 1969 , vol. 25, p. 1807 - 1816
反应条件
[(tetra(4-chlorophenyl)porphyrinato)Al(THF)2][Co(CO)4] in 1,4-dioxane
T=50°C; P=43958.7 Torr; 24 h;
参考文献
Cornell Research Foundation, Inc.; Coates, Geoffrey W.; Rowley, John M.
Patent: US8481756 B1, 2013 ;
Location in patent: Page/Page column 31; 32; 33; 34 ;
