Rammelsberg, C.
Annalen der Physik (Weinheim, Germany), 1838 , vol. 44, p. 559 - 559
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Gmelin Handbook: I: MVol.2, 118, page 499 - 501
in water
decompn. of a white precipitate (formed from iodate and iron(II) salt solution) into iodine and basic iron(II) iodate with coloration to yellow or brown;;
参考文献
Rammelsberg, C.
Annalen der Physik (Weinheim, Germany), 1838 , vol. 44, p. 559 - 559
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Gmelin Handbook: Fe: MVol.B2, 15, page 343 - 345
in not given
formation of a white precipitate from FeSO4- solution and alkali iodate and decomposition under brown coloration into iodine and basic iron(III) iodate;;
参考文献
Rammelsberg, C.
Annalen der Physik (Weinheim, Germany), 1838 , vol. 44, p. 559 - 559
Full Text Show Details
Gmelin Handbook: Fe: MVol.B2, 15, page 343 - 345
acetic acid in water
Kinetics; byproducts: H2O; NH2OH was reacted with IO3(1-) in H2O soln. in the closed reaction vessel at 25°C, pH was adjusted to 2.5 with CH3COOH, the dependence of the rate constant on NH2OH concn. was studied;
参考文献
Beck, Mihaly T.; Rabai, Gyula
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1982 , p. 1687 - 1690
in water
Kinetics; React. in aq. soln. at 25°C, IO3(1-) in stoich. excess over SCN(1-), ionic strength 0.2 M (NaClO4).; UV/VIS-spectroscopy at 460 nm.;
in water
Kinetics; byproducts: H20, H(1+); in a continuous-flow stirred tank reactor at 25° C; various pH and various initial concentration of NH3OH(1+) yields various amounts of N2O, N2, NOH, I(1-) and I2 (oscillatory system); products not isolated; determination of concentration of I(1-) with a Orion iodide-selective electrode; spectrophotometrically determination von I2;
参考文献
Rabai, Gyula; Epstein, Irving R.
Journal of Physical Chemistry, 1990 , vol. 94, # 16 p. 6361 - 6365
