sodium carbonate; tetrakis (triphenylphosphine) palladium (0) in ethanol; hexane; dichloromethane; water; toluene

manganese; cobalt (II) bromide; triphenylphosphine; trifluoroacetic acid in pyridine; N,N-dimethyl-formamide T=50°C;

tetrabutylammomium bromide; palladium diacetate in tetrahydrofuran T=20°C; Negishi coupling; 4 h; Inert atmosphere;

pyridine; tetra-n-butylammonium tetrafluoroborate in acetonitrile T=20°C; Electrolysisiron rod as anode; stainless steel grid as cathode;

1: 1-iodo-2-methoxybenzene With diethylzinc; 1-tert-butyl-4,4,4-tris(dimethylamino)-2,2-bis[tris(dimethylamino)-phosphoranylidenamino]-2Λ54Λ5-catenadi(phosphazene) in hexane; N,N-dimethyl acetamide T=20°C; 24 h; Inert atmosphere; 2: 4-iodobenzoic acid ethyl ester in hexane; N,N-dimethyl acetamide T=20°C; 15 h; Inert atmosphere; 3: With chloranil in hexane; N,N-dimethyl acetamide T=2 - 20°C;

bis-triphenylphosphine-palladium(II) chloride; n-butyllithium; diisobutylaluminium hydride; zinc(II) chloride Multistep reaction;

hydrogenchloride Combinatorial reaction / High throughput screening (HTS); Product distribution / selectivity;