顺,顺-1,5-环辛二烯合成路线 （共 287 条）
反应条件
[BMIM][NTf2]; [(COD)Ir(PPh3)2][NTf2] T=140°C; 5 h; Product distribution; Further Variations:CatalystsTemperatures;
参考文献
Hintermair, Ulrich; Gutel, Thibaut; Slawin, Alexandra M.Z.; Cole-Hamilton, David J.; Santini, Catherine C.; Chauvin, Yves
Journal of Organometallic Chemistry, 2008 , vol. 693, # 14 p. 2407 - 2414
反应条件
bis(1,5-cyclooctadiene)nickel (0); boron trifluoride diethyl etherate Inert atmosphere;
参考文献
Saraev; Kraikivskii; Matveev; Bocharova; Petrovskii; Zelinskii; Vilms; Klein, Hans-Friedrich
Journal of Molecular Catalysis A: Chemical, 2010 , vol. 315, # 2 p. 231 - 238
反应条件
bis(1,5-cyclooctadiene)nickel (0); boron trifluoride diethyl etherate Inert atmosphere;
参考文献
Saraev; Kraikivskii; Matveev; Bocharova; Petrovskii; Zelinskii; Vilms; Klein, Hans-Friedrich
Journal of Molecular Catalysis A: Chemical, 2010 , vol. 315, # 2 p. 231 - 238
反应条件
sodium acetate; copper dichloride; palladium dichloride in dichloromethane T=100°C; P=3127.8 Torr; 24 h; other Pd(II)-catalysts, other oxidants, var. conditions; Product distributionMechanism;
参考文献
Collection of Czechoslovak Chemical Communications, , vol. 57, # 11 p. 2374 - 2382
反应条件
in tetrahydrofuran reaction in a calorimeter under argon;
参考文献
Inorganic Chemistry, , vol. 27, p. 81 - 85
反应条件
1: O3 2: TsOH / 10 h / Ambient temperature 3: 98 percent / (i-Bu)2AlH / toluene; tetrahydrofuran / -10 °C 4: pyridine / 15 h / -10 °C 5: 75 percent / Li2CuCl4 / diethyl ether; tetrahydrofuran / 2 h / -78 °C 6: aq.HCl / acetone / 4 h / 25 °C 7: (i-Bu)2AlH / diethyl ether; toluene / -10 deg C, 1.5h; 25 deg C,15h 8: pyridine 9: diethyl ether; tetrahydrofuran / 2 h / -78 °C View Scheme
参考文献
Odinokov, V.N.; Tolstikov, G.A.; Galeyeva, R.I.; Kargapol'tseva, T.A.
Tetrahedron Letters, 1982 , vol. 23, # 13 p. 1371 - 1372
反应条件
2: ZnCl2, H2O / dioxane / 22 h / Heating 3: K2CO3 / acetone / 9 h / Heating 4: anhydr. chloral, NEt3 / toluene / 6 h / 65 °C 5: 48 percent / imidazole, NEt3 / dimethylformamide / 1.5 h / 10 deg C -> room temperature View Scheme
参考文献
Dygos; Adamek; Babiak; Behling; Medich; Ng; Wieczorek
Journal of Organic Chemistry, 1991 , vol. 56, # 7 p. 2549 - 2552
反应条件
BACH-EItrade; in 1,4-dioxane hydroboration; Heating;
参考文献
Brown, Herbert C.; Kanth, Josyula V. B.; Zaidlewicz, Marek
Tetrahedron, 1999 , vol. 55, # 19 p. 5991 - 6000
反应条件
BACH-EItrade; in 1,4-dioxane T=20°C; hydroboration; 1 h; Title compound not separated from byproducts;
参考文献
Brown, Herbert C.; Kanth, Josyula V. B.; Zaidlewicz, Marek
Tetrahedron, 1999 , vol. 55, # 19 p. 5991 - 6000
参考文献
Enders, Dieter; Schuesseler, Thomas
Synthesis, 2002 , # 15 p. 2280 - 2288
