顺,顺-1,5-环辛二烯合成路线 （共 287 条）
参考文献
Bloodworth, A.J.; Khan, Jamil A.; Loveitt, M.E.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1981 , p. 621 - 632
反应条件
(i) LiCl, PdCl2, (ii) /BRN= 2036542/, (iii) NaBH4; Multistep reaction;
参考文献
Kasahara,A. et al.
Bulletin of the Chemical Society of Japan, 1974 , vol. 47, p. 1967 - 1970
反应条件
1: 55 g / Me4Sn / MoCl5/SiO2 / toluene / 24 h / 20 °C
2: 90 percent / LiAlH4; Cp2ZrCl2 / tetrahydrofuran / 1 h / 20 °C
3: 55 percent / 9-BBN; t-BuOK / 2-methyl-propan-2-ol
4: 95 percent / LiAlH4 / tetrahydrofuran / 1 h / 50 °C
5: 95 percent / pyridine / hexane / 2 h
View Scheme
参考文献
Bykov; Butenko; Egupova; Finkelshtein
Russian Chemical Bulletin, 2000 , vol. 49, # 7 p. 1301 - 1304
反应条件
1: 1.) BH3*THF, 2.) aq. NaOH, 30percent H2O2 / 1.) THF, reflux, 1 h, 2.) reflux
2: pyridinium chlorochromate / CH2Cl2 / 24 h / Heating
View Scheme
参考文献
Lyttle, Matthew; Streitwieser, Andrew; Miller, Michael J.
Journal of Organic Chemistry, 1989 , vol. 54, # 10 p. 2331 - 2335
反应条件
Nitrous oxide
T=220°C; 5 h; pressure;
参考文献
Starokon; Dubkov; Babushkin; Parmon; Panov
Advanced Synthesis and Catalysis, 2004 , vol. 346, # 2-3 p. 268 - 274
反应条件
1: HBr, AcOH
2: NaOMe / methanol
3: 1.) Hg(O2CCF3)2, 80percentH2O2, 2.) NaBH4, aq. NaOH / 1.) dichloromethane, ice bath, 30 min 2.) ice and salt bath - room temperature
View Scheme
参考文献
Bloodworth, A.J.; Khan, Jamil A.; Loveitt, M.E.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1981 , p. 621 - 632
参考文献
Anet, Frank A. L.; Ghiaci, Mehran
Journal of the American Chemical Society, 1980 , vol. 102, # 8 p. 2528 - 2533
反应条件
hydrogen; ruthenium palladium
T=99.9 - 299.9°C; hydrogenation of cyclopentadiene, cyclooctadiene and isoprene, hydrogenolysis of propane; effect of the nature of reagents, temperature and number of tests on catalytic activity of membrane catalyst;
参考文献
Ermilova, M. M.; Orekhova, N. V.; Skakunova, E. V.; Gryaznov, V. M.
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), 1988 , vol. 37, p. 637 - 640
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1988 , # 4 p. 750 - 755
反应条件
potassium tert-butylate
1.) CH2Cl2, -15 deg C, 2 h, irradiation, 2.) THF, t-BuOH, 0 deg C; Yield given. Multistep reaction. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Block,E.; Aslam,M.
Journal of the American Chemical Society, 1983 , vol. 105, p. 6165
反应条件
hydrogenchloride; nitrosyl chloride in diethyl ether
参考文献
Biela,R. et al.
Journal fuer Praktische Chemie (Leipzig), 1966 , vol. 33, p. 282 - 292
