顺,顺-1,5-环辛二烯合成路线 （共 287 条）
反应条件
carbon monoxide; hydrogen; Rh{OC(O)Me}(CO)(PPh3)2 in benzene
T=70°C; P=22800 Torr; 10 h; autoclave;
参考文献
Zakharkin, L. I.; Guseva, V. V.; Kaverin, V. V.; Yur'ev, V. P.
Journal of Organic Chemistry USSR (English Translation), 1987 , vol. 23, # 6 p. 1201 - 1202
Zhurnal Organicheskoi Khimii, 1987 , vol. 23, # 6 p. 1328 - 1329
反应条件
sodium hydroxide; sodium tetrahydroborate; potassium chloride; mercury(II) diacetate; dihydrogen peroxide
Yield given. Multistep reaction. Further byproducts given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Bloodworth, A.J.; Khan, Jamil A.; Loveitt, M.E.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1981 , p. 621 - 632
反应条件
sodium hydroxide; sodium tetrahydroborate; potassium chloride; mercury(II) diacetate; dihydrogen peroxide
Yield given. Multistep reaction. Further byproducts given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Bloodworth, A.J.; Khan, Jamil A.; Loveitt, M.E.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1981 , p. 621 - 632
反应条件
sodium hydroxide; sodium tetrahydroborate; potassium chloride; mercury(II) diacetate; dihydrogen peroxide
Yield given. Multistep reaction. Further byproducts given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Bloodworth, A.J.; Khan, Jamil A.; Loveitt, M.E.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1981 , p. 621 - 632
反应条件
sodium hydroxide; sodium tetrahydroborate; dihydrogen peroxide; mercury(II) trifluoroacetate; benzene
multistep reaction; (per)oxymercuriation of various cyclo-octadienes followed by reduction, influence of mercury(II) salt and reaction conditions; Product distribution;
参考文献
Bloodworth, A.J.; Khan, Jamil A.; Loveitt, M.E.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1981 , p. 621 - 632
反应条件
sodium hydroxide; sodium tetrahydroborate; potassium chloride; mercury(II) diacetate; dihydrogen peroxide
multistep reaction; (per)oxymercuriation of various cyclo-octadienes followed by reduction, influence of mercury(II) salt and reaction conditions; Product distribution;
参考文献
Bloodworth, A.J.; Khan, Jamil A.; Loveitt, M.E.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1981 , p. 621 - 632
反应条件
in dichloromethane
T=0 - 10°C; 2 h; Irradiation;
参考文献
Ashcroft, Martyn M.; Bougeard, Peter; Bury, Adrian; Cooksey, Christopher J.; Johnson, Michael D.; et al.
Journal of Organic Chemistry, 1984 , vol. 49, # 10 p. 1751 - 1761
反应条件
phenyl isocyanate; triethylamine
参考文献
Williams, Peter D.; LeGoff, Eugene
Heterocycles, 1984 , vol. 22, # 2 p. 269 - 270
反应条件
1: 74 percent / Et3N, PhNCO
2: 89 percent / γ-MnO2 / benzene / Heating
3: 96 percent / m-CPBA / CHCl3 / 0 °C
4: 96 percent / H5IO6 / H2O / 0.33 h / 85 °C / pH=7.1
View Scheme
参考文献
Williams, Peter D.; LeGoff, Eugene
Heterocycles, 1984 , vol. 22, # 2 p. 269 - 270
反应条件
1: 74 percent / Et3N, PhNCO
2: 89 percent / γ-MnO2 / benzene / Heating
3: 96 percent / m-CPBA / CHCl3 / 0 °C
4: 96 percent / H5IO6 / H2O / 0.33 h / 85 °C / pH=7.1
5: 97 percent / tetrahydrofuran / 12 h / 25 °C
View Scheme
参考文献
Williams, Peter D.; LeGoff, Eugene
Heterocycles, 1984 , vol. 22, # 2 p. 269 - 270
