三(三苯基膦)二氯化钌(II)合成路线 （共 36 条）
反应条件
in methanol RuCl3*3H2O and PPh3 refluxed in anhyd. MeOH for 2.5 h; according to L. A. Ortiz-Frade et al., Inorg. Chem., 2003, 42, 1825-1834 and P. S. Hallman et al., Inorg. Synth., 1970, 12, 237-240; decanted; solid loaded on Schlenk frit; washed with ether; dried under vac. overnight;;
参考文献
Shaw, Anthony P.; Ryland, Bradford L.; Norton, Jack R.; Buccella, Daniela; Moscatelli, Alberto
Inorganic Chemistry, 2007 , vol. 46, # 14 p. 5805 - 5812
反应条件
2-pyridyl methyl ketone in chloroform byproducts: CH2Cl2; 4 mol percent MeC(O)C5H4N;
参考文献
Vriends, Rob. C. J.; Koten, Gerard van; Vrieze, Kees
Inorganica Chimica Acta, 1978 , vol. 26, p. L29 - L31
反应条件
in methanol RuCl3(H2O)3 was dissolved in MeOH, PPh3 was added, heated under reflux for 4 h; filtered, washed with Et2O; elem. anal.;
参考文献
Ortiz-Frade, Luis A.; Ruiz-Ramirez, Lena; Gonzalez, Ignacio; Marin-Becerra, Armando; Alcarazo, Manuel; Alvarado-Rodriguez, Jose G.; Moreno-Esparza, Rafael
Inorganic Chemistry, 2003 , vol. 42, # 6 p. 1825 - 1834
反应条件
PPh3 in ethanol addn. of six-fold excess PPh3 to RuCl3 soln., refluxing (inert atmosphere, 3.5-4 h); washing (MeOH, ether), drying (vac., 60°C);
参考文献
Russian Journal of Inorganic Chemistry (Translation of Zhurnal Neorganicheskoi Khimii), , vol. 26, p. 1334 - 1336
Zhurnal Neorganicheskoi Khimii, , vol. 26, p. 2483 - 2486
反应条件
triphenylphosphine in methanol according to Khan, M. I., et al., Ind. J. Chem.. Sect. A, 1983, 22, 417; molar ratio RuCl3*nH2O/PPh3 1:5, refluxing (stirring, 2-5 min), refluxing with N-methyl-N-nitrosotoluene-p-sulphonamide (2 h);
参考文献
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), , p. 1139 - 1142
反应条件
in chloroform-d1 further products; standed at room temp. for 3 d; not isolated, detected by NMR;
参考文献
European Journal of Inorganic Chemistry, , # 12 p. 2542 - 2552
反应条件
in tetrahydrofuran byproducts: Ph3PO, PPh3; (Ar); standard Schlenk technique; Ru complex was treated with ligand (1 equiv.) in THF; NMR monitoring;
参考文献
Journal of Organometallic Chemistry, , vol. 690, # 1 p. 1 - 13
反应条件
in ethanol react. in boiling C2H5OH; isolation of Ru-compd., other products detd. by GC;
参考文献
Journal of molecular catalysis, , vol. 50, # 3 p. 333 - 341
反应条件
H2; triethylamine in toluene Hallman, P.S.; McGarvey, B. R.; Wilkinson, G. J. Chem. Soc. A 1968, 3143-3150;
参考文献
Pez, Guido P.; Grey, Roger A.; Corsi, Jeff
Journal of the American Chemical Society, 1981 , vol. 103, # 25 p. 7528 - 7535
反应条件
in acetone boiling in degassed acetone for 12 h with reflux;; washing with H2O and ether;;
参考文献
Gmelin Handbook: Ru: SVol., 156, page 429 - 431
