三(三苯基膦)二氯化钌(II)合成路线 （共 36 条）
反应条件
1-decene; 1,1,3,3-tetramethyldisiloxane in toluene mixt. of tetramethyldixiloxane, 1-decene and Ru-complex in unhyd. toluene stirred at room temp., evacuated, refilled with N2 three times, stirred at 100°C for 5 d; centrifuged, decanted, washed by toluene, centrifuged twice, dried indervac.; detd. by XRD, TEM;
参考文献
Journal of Physical Chemistry B, , vol. 109, # 35 p. 16644 - 16649
参考文献
Gomez-Bengoa, Enrique; Cuerva, Juan M.; Mateo, Cristina; Echavarren, Antonio M.
Journal of the American Chemical Society, 1996 , vol. 118, # 36 p. 8553 - 8565
反应条件
1: tetrahydrofuran 2: N2 / tetrahydrofuran 3: triphenylphosphine / tetrahydrofuran View Scheme
参考文献
Chan, Albert S. C.; Shieh, Huey-Sheng
Journal of the Chemical Society, Chemical Communications, 1985 , # 20 p. 1379 - 1380
反应条件
in benzene stirring (16 h); filtration, partial evapn., treatment with petroleum (crystn.); product mixt. not sepd., detd. by (1)H-NMR spectroscopy;
参考文献
Cole-Hamilton, David J.; Wilkinson, Geoffrey
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1979 , p. 1283 - 1289
反应条件
in acetone a soln. of complexes in acetone was heated under reflux for 3 h; ppt. was filtered off and removed, filtrate was cooled and ppt. was formed, washed with acetone and dried in vac., after filtrate was reduced to dryness, washed with hexane and recrystn.. from CH2Cl2/hexane gave second product; NMR, elem.anal.;
参考文献
Inorganica Chimica Acta, , vol. 103, p. 83 - 94
反应条件
in dichloromethane a soln. of complexes in CH2Cl2 was heated under reflux for 3 h; solvent was removed and benzene was added to oil, ppt. was filtered offand washed with benzene, dried in vac., filtrate was reduced to drynessand recrystd. from CH2Cl2/hexane to dive the 2-d product; IR, NMR;
参考文献
Inorganica Chimica Acta, , vol. 103, p. 83 - 94
反应条件
in acetone a soln. of complexes in acetone was heated under reflux for 3 h; ppt. was filtered off and removed, filtrate was cooled and ppt. was formed, washed with acetone and dried in vac., after filtrate was reduced to dryness, washed with hexane and recrystn.. from CH2Cl2/hexane gave second product; NMR, elem.anal.;
参考文献
Inorganica Chimica Acta, , vol. 103, p. 83 - 94
反应条件
in dichloromethane a soln. of complexes in CH2Cl2 was heated under reflux for 3 h; solvent was removed and benzene was added to oil, ppt. was filtered offand washed with benzene, dried in vac., filtrate was reduced to drynessand recrystd. from CH2Cl2/hexane to dive the 2-d product; IR, NMR;
参考文献
Inorganica Chimica Acta, , vol. 103, p. 83 - 94
反应条件
methanol; hexafluorophosphate in methanol byproducts: methyl formate, dimethoxymethane; 150.grad.C, 18h, under Ar;; evapn., IR, NMR;;
参考文献
Journal of Organometallic Chemistry, , vol. 291, p. C13 - C14
反应条件
methanol; cyclohexanone in methanol heated at 110-150°C for different time; nature of products depended on precise condition used; monitored by IR;
参考文献
Journal of Organometallic Chemistry, , vol. 289, p. 385 - 396
