三(三苯基膦)二氯化钌(II)合成路线 （共 36 条）
反应条件
methanol; hexafluorophosphate in methanol byproducts: methyl formate, dimethoxymethane; 150.grad.C, 18h, under Ar;; evapn., IR, NMR;;
参考文献
Journal of Organometallic Chemistry, , vol. 291, p. C13 - C14
反应条件
in acetone a soln. of complexes in acetone was heated under reflux for 3 h; ppt. was filtered off and removed, filtrate was cooled and ppt. was formed, washed with acetone and dried in vac., after filtrate was reduced to dryness, washed with hexane and recrystn.. from CH2Cl2/hexane gave second product; NMR, elem.anal.;
参考文献
Inorganica Chimica Acta, , vol. 103, p. 83 - 94
反应条件
in dichloromethane a soln. of complexes in CH2Cl2 was heated under reflux for 3 h; solvent was removed and benzene was added to oil, ppt. was filtered offand washed with benzene, dried in vac., filtrate was reduced to drynessand recrystd. from CH2Cl2/hexane to dive the 2-d product; IR, NMR;
参考文献
Inorganica Chimica Acta, , vol. 103, p. 83 - 94
反应条件
KOH in ethanol soln. of KOH in EtOH added to refluxing suspn. of Ru complex and indenein EtOH under N2, refluxed for 4 h; cooled, filtered, extd. (CH2Cl2), filtered, added MeOH, ppt. filtered after 30 min, washed with MeOH, Et2O, dried in vac.; purified by extn. (acetone), evapd., recrystd. (CH2Cl2/Et2O); elem. anal.;
参考文献
Oro, Luis A.; Ciriano, Miguel A.; Campo, Marina; Foces-Foces, Concepcion; Cano, Felix H.
Journal of Organometallic Chemistry, 1985 , vol. 289, p. 117 - 132
反应条件
hydrogen in ethanol; benzene (H2 as protect. gas); dropwise addn. of ethanolic NaBH4 soln. to benzene/ethanol soln. of Ru complex over 30 min; H2 bubbled through soln. for ca. 2 h; ppt. removed, filtrate stored 2 weeks under pentane: small red needles of (PPh3)2HRu(μ-H)3Ru(PPh3)3 and less dense white RuH2(CO)(PPh3)3 formed; soln. + CO complex decanted, Ru2 complex washed with EtOH, stored under Ar;
参考文献
Organometallics, , vol. 10, p. 1033 - 1038
反应条件
methanol; cyclohexanone in methanol heated at 110-150°C for different time; nature of products depended on precise condition used; monitored by IR;
参考文献
Journal of Organometallic Chemistry, , vol. 289, p. 385 - 396
反应条件
methanol or ethanol in benzene addn. of NaBH4 and methanol or ethanol to a soln. of (RuCl2(C18H15P)3) in benzene; boiling the suspension under H2 atmosphere;; cooling down in a stream of H2; pptn.; washing with ether and drying in vac.;;
参考文献
Gmelin Handbook: Ru: SVol., 189, page 508 - 510
反应条件
in further solvent(s) heating in dibenzyl ether at 190°C for 45 min; cooling with addn. of Et2O;
参考文献
Speier, Gabor; Marko, Laszlo
Journal of Organometallic Chemistry, 1981 , vol. 210, # 2 p. 253 - 262
反应条件
in toluene T=100°C; 6 h;
参考文献
FIRMENICH SA
Patent: WO2006/106483 A1, 2006 ;
Location in patent: Page/Page column 16; 18-19 ;
反应条件
in benzene dissociation in benzene soln.;;
参考文献
Gmelin Handbook: Ru: SVol., 154, page 425 - 426
