三(三苯基膦)二氯化钌(II)合成路线 （共 36 条）
反应条件
in dichloromethane
T=40°C; 1.83333 h;
参考文献
LANXESS DEUTSCHLAND GMBH
Patent: US2009/76226 A1, 2009 ;
Location in patent: Page/Page column 16-17 ;
反应条件
potassium tert-butoxide in tetrahydrofuran
byproducts: KCl, triphenylphosphine; under Ar; KOC(CH3)3 added to soln. of the acetic acid derivative in THF,mixt. stirred at room temp. for 1 h, Ru complex added to suspn., stirre d at room temp. for 0.5 h; evapd. under vac., residue washed with water and Et2O, dried under vac.;
参考文献
Lopez-Hernandez, Alberto; Mueller, Rainer; Kopf, Henning; Burzlaff, Nicolai
European Journal of Inorganic Chemistry, 2002 , # 3 p. 671 - 677
反应条件
in tetrahydrofuran
byproducts: PPh3; stirring (110°C, 10 h); filtering, washing (pentane, -30°C), drying (vac.); elem. anal.;
参考文献
Van Der Boom, Milko E.; Kraatz, Heinz-Bernhard; Hassner, Lawrence; Ben-David, Yehoshoa; Milstein, David
Organometallics, 1999 , vol. 18, # 19 p. 3873 - 3884
反应条件
in tetrahydrofuran
byproducts: PPh3; stirring (110°C, 10 h); filtering, washing (pentane, -30°C), drying (vac.);
参考文献
Van Der Boom, Milko E.; Kraatz, Heinz-Bernhard; Hassner, Lawrence; Ben-David, Yehoshoa; Milstein, David
Organometallics, 1999 , vol. 18, # 19 p. 3873 - 3884
反应条件
in tetrahydrofuran
byproducts: C2H6, PPh3; H2-atmosphere (30 - 35 psi); stirring (110°C, 5 d, Fischer - Porter pressure vessel);
参考文献
Van Der Boom, Milko E.; Kraatz, Heinz-Bernhard; Hassner, Lawrence; Ben-David, Yehoshoa; Milstein, David
Organometallics, 1999 , vol. 18, # 19 p. 3873 - 3884
反应条件
in tetrahydrofuran
byproducts: CH4, PPh3; H2-atmosphere (30 - 35 psi); Fischer - Porter pressure vessel (110°C, 17 h), evapn. (vac.); washing (pentane, -30°C); elem. anal.;
参考文献
Van Der Boom, Milko E.; Kraatz, Heinz-Bernhard; Hassner, Lawrence; Ben-David, Yehoshoa; Milstein, David
Organometallics, 1999 , vol. 18, # 19 p. 3873 - 3884
